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• W2202808081 abstract "Self-assembled microstructures of an amphiphilic diarylethene featuring an alkyl chain and triethylene glycol groups showed a photoinduced reversible morphological change in water. Reversible photoisomerization of the core diarylethene gave rise to a reversible morphological transformation between colorless microspheres and colored fibers. When colorless microspheres were irradiated with UV light, colored fibers were formed, and when the colored fibers were irradiated with visible light, the spheres were restored to their original positions where the spheres originally existed. This system showed reversible morphological change through not only photoirradiation but also temperature change. These behaviors can be interpreted as a phase transition between the sphere and fiber states. The dynamic process of the phase transition was monitored by polarized optical microscopy (POM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). It was revealed that the formation of fibers upon UV irradiation occurred radially at the surface of the sphere and the formation of the spheres upon visible-light irradiation occurred at the middle of the fiber. The unique photoinduced mechanical motion provides useful information for the design of sophisticated photoactuators." @default.
• W2202808081 created "2016-06-24" @default.
• W2202808081 creator A5028071882 @default.
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• W2202808081 creator A5048574595 @default.
• W2202808081 creator A5076164664 @default.
• W2202808081 creator A5079141391 @default.
• W2202808081 date "2015-02-17" @default.
• W2202808081 modified "2023-10-13" @default.
• W2202808081 title "Photoinduced Macroscopic Morphological Transformation of an Amphiphilic Diarylethene Assembly: Reversible Dynamic Motion" @default.
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• W2202808081 doi "https://doi.org/10.1021/ja512924q" @default.
• W2202808081 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25650962" @default.
• W2202808081 hasPublicationYear "2015" @default.
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