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• W2203131805 endingPage "113401" @default.
• W2203131805 startingPage "113401" @default.
• W2203131805 abstract "A state-to-state dynamics analysis for the Li + HF (v = 0, j = 0) → LiF (v', j') + H collision reaction has been performed through quasiclassical trajectory (QCT) calculations. It is found that the differential cross section (DCS) of the LiF products from the title reaction is preferentially backward scattering for v' = 0, yet forward scattering for v' = 1 and 2. For v' = 3, the DCS exhibits forward, backward, and sideways scatterings. The variation of the internuclear distances and angles along the propagation time reveals that more than 99.08% of reaction trajectories undergo the direct reaction mechanism. The values of the polarization parameters a1−{1} and a0{2} demonstrate that the product rotational angular moment j' is not only aligned perpendicular to the reagent relative velocity vector k, but also oriented along the negative y axis. These product polarization results agree well with the recent quantum mechanical studies. The mechanism of these results was proposed and discussed in detail." @default.
• W2203131805 created "2016-06-24" @default.
• W2203131805 creator A5086578535 @default.
• W2203131805 date "2013-11-01" @default.
• W2203131805 modified "2023-10-04" @default.
• W2203131805 title "Product polarization and mechanism of Li + HF ( <i>v</i> = 0, <i>j</i> = 0) → LiF ( <i>v′</i> , <i>j′</i> ) + H collision reaction" @default.
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• W2203131805 doi "https://doi.org/10.1088/1674-1056/22/11/113401" @default.
• W2203131805 hasPublicationYear "2013" @default.
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