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- W2204111189 abstract "An ABCD 4-miktoarm star quaterpolymer with A = poly(ε-caprolactone) (PCL), B = poly(tert-butyl acrylate) (PtBA), C = polystyrene (PS) and D = poly(methyl methacrylate) (PMMA) arms was prepared using the Diels–Alder reaction strategy. Firstly, PCL with anthracene (PCL-Anth) and PtBA with furan-protected maleimide (PtBA-MI) end-functionalities were synthesized separately via ring-opening polymerization of ε-CL and atom transfer radical polymerization of tBA, respectively. These homo-polymers were linked via the Diels–Alder click reaction in toluene at 100°C in order to give PCL-b-PtBA co-polymer. Next, this block co-polymer is utilized successively as macroinitiator in nitroxide-mediated radical polymerization of styrene and in free radical photo-polymerization of MMA in order to achieve the PCL-PtBA-PS-PMMA 4-miktoarm star quaterpolymer." @default.
- W2204111189 created "2016-06-24" @default.
- W2204111189 creator A5034220229 @default.
- W2204111189 creator A5051308926 @default.
- W2204111189 creator A5069397352 @default.
- W2204111189 date "2009-01-01" @default.
- W2204111189 modified "2023-10-17" @default.
- W2204111189 title "Synthesis of an ABCD 4-Miktoarm Star Quaterpolymer Through a Diels–Alder Click Reaction" @default.
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- W2204111189 doi "https://doi.org/10.1163/156855508x391158" @default.
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