Matches in SemOpenAlex for { <https://semopenalex.org/work/W2204982288> ?p ?o ?g. }
- W2204982288 endingPage "639" @default.
- W2204982288 startingPage "635" @default.
- W2204982288 abstract "Kinetic and thermodynamic aspects of the retro cheletropic reaction of sulfur dioxide extrusion have been investigated. The interaction of the X–S bond (X=NH, S, O and CH 2 ) and oxygen lone pairs of SO 2 showed remarkable stereoelectronic effects and its correlation with the difference between computed and empirical bond length (Δl) have been analysed. The facility of the reaction in the case of four derivatives (X=NH, S, O and CH 2 ) has been investigated from the viewpoint of product delocalisation energy. In addition, substitution effects have been studied on the relative Gibbs free energy of reaction for the oxygen derivative (X=O). Moreover, a correlation has been found between the Gibbs free energy of reaction in the presence of the substituent and Δl as a criterion for the value of the interaction between the X–S bond and oxygen lone pairs of the SO 2 group. Finally, a new method based on electron density has been used for evaluation of the synchronicity values of the reaction. According to the corresponding diagrams, the calculated synchronicity values of the Wiberg bond indices and electron density are in good agreement." @default.
- W2204982288 created "2016-06-24" @default.
- W2204982288 creator A5004822240 @default.
- W2204982288 creator A5012676087 @default.
- W2204982288 creator A5038382890 @default.
- W2204982288 creator A5072876335 @default.
- W2204982288 creator A5088201837 @default.
- W2204982288 creator A5091709068 @default.
- W2204982288 date "2015-11-01" @default.
- W2204982288 modified "2023-10-05" @default.
- W2204982288 title "Stereoelectronic Effects: A Powerful Concept in Explaining Kinetic and Thermodynamic Aspects of Retro Cheletropic Reactions" @default.
- W2204982288 cites W1574356778 @default.
- W2204982288 cites W1976978717 @default.
- W2204982288 cites W1981883219 @default.
- W2204982288 cites W2005540985 @default.
- W2204982288 cites W2008844584 @default.
- W2204982288 cites W2021725430 @default.
- W2204982288 cites W2024896976 @default.
- W2204982288 cites W2031861980 @default.
- W2204982288 cites W2033813290 @default.
- W2204982288 cites W2037327470 @default.
- W2204982288 cites W2038767330 @default.
- W2204982288 cites W2042944554 @default.
- W2204982288 cites W2052707407 @default.
- W2204982288 cites W2085966856 @default.
- W2204982288 cites W2089759714 @default.
- W2204982288 cites W2123802716 @default.
- W2204982288 cites W2134670420 @default.
- W2204982288 cites W2137339116 @default.
- W2204982288 cites W2139740741 @default.
- W2204982288 cites W2139916893 @default.
- W2204982288 cites W2141293385 @default.
- W2204982288 cites W2142362892 @default.
- W2204982288 cites W2171093181 @default.
- W2204982288 cites W2320141164 @default.
- W2204982288 cites W2323795606 @default.
- W2204982288 cites W2949227545 @default.
- W2204982288 cites W4239931528 @default.
- W2204982288 cites W4249005344 @default.
- W2204982288 cites W4293033195 @default.
- W2204982288 doi "https://doi.org/10.3184/174751915x14448273156159" @default.
- W2204982288 hasPublicationYear "2015" @default.
- W2204982288 type Work @default.
- W2204982288 sameAs 2204982288 @default.
- W2204982288 citedByCount "1" @default.
- W2204982288 countsByYear W22049822882020 @default.
- W2204982288 crossrefType "journal-article" @default.
- W2204982288 hasAuthorship W2204982288A5004822240 @default.
- W2204982288 hasAuthorship W2204982288A5012676087 @default.
- W2204982288 hasAuthorship W2204982288A5038382890 @default.
- W2204982288 hasAuthorship W2204982288A5072876335 @default.
- W2204982288 hasAuthorship W2204982288A5088201837 @default.
- W2204982288 hasAuthorship W2204982288A5091709068 @default.
- W2204982288 hasBestOaLocation W22049822881 @default.
- W2204982288 hasConcept C121332964 @default.
- W2204982288 hasConcept C135889238 @default.
- W2204982288 hasConcept C146477669 @default.
- W2204982288 hasConcept C147597530 @default.
- W2204982288 hasConcept C147789679 @default.
- W2204982288 hasConcept C178790620 @default.
- W2204982288 hasConcept C185592680 @default.
- W2204982288 hasConcept C2778689049 @default.
- W2204982288 hasConcept C32909587 @default.
- W2204982288 hasConcept C46000676 @default.
- W2204982288 hasConcept C62520636 @default.
- W2204982288 hasConcept C71240020 @default.
- W2204982288 hasConcept C97355855 @default.
- W2204982288 hasConceptScore W2204982288C121332964 @default.
- W2204982288 hasConceptScore W2204982288C135889238 @default.
- W2204982288 hasConceptScore W2204982288C146477669 @default.
- W2204982288 hasConceptScore W2204982288C147597530 @default.
- W2204982288 hasConceptScore W2204982288C147789679 @default.
- W2204982288 hasConceptScore W2204982288C178790620 @default.
- W2204982288 hasConceptScore W2204982288C185592680 @default.
- W2204982288 hasConceptScore W2204982288C2778689049 @default.
- W2204982288 hasConceptScore W2204982288C32909587 @default.
- W2204982288 hasConceptScore W2204982288C46000676 @default.
- W2204982288 hasConceptScore W2204982288C62520636 @default.
- W2204982288 hasConceptScore W2204982288C71240020 @default.
- W2204982288 hasConceptScore W2204982288C97355855 @default.
- W2204982288 hasIssue "11" @default.
- W2204982288 hasLocation W22049822881 @default.
- W2204982288 hasOpenAccess W2204982288 @default.
- W2204982288 hasPrimaryLocation W22049822881 @default.
- W2204982288 hasRelatedWork W1972116396 @default.
- W2204982288 hasRelatedWork W1976203909 @default.
- W2204982288 hasRelatedWork W2024801531 @default.
- W2204982288 hasRelatedWork W2063869562 @default.
- W2204982288 hasRelatedWork W2089483114 @default.
- W2204982288 hasRelatedWork W2363151802 @default.
- W2204982288 hasRelatedWork W2386285247 @default.
- W2204982288 hasRelatedWork W2953261074 @default.
- W2204982288 hasRelatedWork W2444094057 @default.
- W2204982288 hasRelatedWork W2469544680 @default.
- W2204982288 hasVolume "39" @default.
- W2204982288 isParatext "false" @default.
- W2204982288 isRetracted "false" @default.
- W2204982288 magId "2204982288" @default.