Matches in SemOpenAlex for { <https://semopenalex.org/work/W2205335144> ?p ?o ?g. }
- W2205335144 abstract "Rare earth chemistry has witnessed remarkable advances in recent years. In particular, ancillary ligands other than cyclopentadienyl derivatives have been introduced to the organometallic chemistry, and their complexes exhibit distinct reactivity and properties compared to the metallocene or half-sandwiched analogs. This chapter reviews arene-bridged rare earth complexes with an emphasis on those compounds obtained by reduction reactions. A particular emphasis is placed on rare earth complexes supported by 1,1'-ferrocenediyl diamides since they show the most diverse chemistry with arenes: Fused arenes, such as naphthalene and anthracene, formed inverse-sandwiched complexes, in which the arene is dianionic; weakly conjugated arenes, such as biphenyl, p-terphenyl, and 1,3,5-triphenylbenzene, were unexpectedly reduced by four electrons and led to 6-carbon, 10π-electron aromatic systems; on the contrary, (E)-stilbene, which has a carbon-carbon double bond between the two phenyl rings, could only be reduced by two electrons, which were located on the carbon-carbon double bond instead of the phenyl rings. The reactivity of some rare earth arene-bridged complexes is also discussed with noticeable examples being the activation of white phosphorus (P4) by rare earth naphthalene complexes. Stoichiometric P4 activation led to polyphosphide (P84-P84- or P73-P73-), which could then be transferred to phosphorus-containing organic molecules. © 2014 Elsevier B.V." @default.
- W2205335144 created "2016-06-24" @default.
- W2205335144 creator A5029282916 @default.
- W2205335144 creator A5060873755 @default.
- W2205335144 date "2014-01-01" @default.
- W2205335144 modified "2023-09-26" @default.
- W2205335144 title "Rare Earth Arene-Bridged Complexes Obtained by Reduction of Organometallic Precursors" @default.
- W2205335144 cites W1487424200 @default.
- W2205335144 cites W1493573168 @default.
- W2205335144 cites W1540681742 @default.
- W2205335144 cites W1628811533 @default.
- W2205335144 cites W169320866 @default.
- W2205335144 cites W1964535484 @default.
- W2205335144 cites W1964935178 @default.
- W2205335144 cites W1965076437 @default.
- W2205335144 cites W1965157405 @default.
- W2205335144 cites W1965484920 @default.
- W2205335144 cites W1965952286 @default.
- W2205335144 cites W1966191602 @default.
- W2205335144 cites W1967352022 @default.
- W2205335144 cites W1967871667 @default.
- W2205335144 cites W1968287645 @default.
- W2205335144 cites W1969845922 @default.
- W2205335144 cites W1971249591 @default.
- W2205335144 cites W1972043936 @default.
- W2205335144 cites W1974428011 @default.
- W2205335144 cites W1974752460 @default.
- W2205335144 cites W1975402725 @default.
- W2205335144 cites W1975452682 @default.
- W2205335144 cites W1975500424 @default.
- W2205335144 cites W1975819013 @default.
- W2205335144 cites W1976263143 @default.
- W2205335144 cites W1978334635 @default.
- W2205335144 cites W1978692452 @default.
- W2205335144 cites W1978974168 @default.
- W2205335144 cites W1979044071 @default.
- W2205335144 cites W1981581558 @default.
- W2205335144 cites W1981898910 @default.
- W2205335144 cites W1982520376 @default.
- W2205335144 cites W1983428068 @default.
- W2205335144 cites W1983990514 @default.
- W2205335144 cites W1985542788 @default.
- W2205335144 cites W1986012177 @default.
- W2205335144 cites W1986604666 @default.
- W2205335144 cites W1989066978 @default.
- W2205335144 cites W1990250276 @default.
- W2205335144 cites W1990732449 @default.
- W2205335144 cites W1991188896 @default.
- W2205335144 cites W1992721461 @default.
- W2205335144 cites W1992916301 @default.
- W2205335144 cites W1993682216 @default.
- W2205335144 cites W1994567457 @default.
- W2205335144 cites W1994927639 @default.
- W2205335144 cites W1995662219 @default.
- W2205335144 cites W1995876249 @default.
- W2205335144 cites W1996679562 @default.
- W2205335144 cites W1996988318 @default.
- W2205335144 cites W1997075852 @default.
- W2205335144 cites W1997374390 @default.
- W2205335144 cites W1997652393 @default.
- W2205335144 cites W1997993799 @default.
- W2205335144 cites W1998333844 @default.
- W2205335144 cites W1998468853 @default.
- W2205335144 cites W1999290148 @default.
- W2205335144 cites W1999751891 @default.
- W2205335144 cites W1999901687 @default.
- W2205335144 cites W2000885275 @default.
- W2205335144 cites W2001011492 @default.
- W2205335144 cites W2002286117 @default.
- W2205335144 cites W2002384391 @default.
- W2205335144 cites W2002509876 @default.
- W2205335144 cites W2003485802 @default.
- W2205335144 cites W2003652923 @default.
- W2205335144 cites W2003655767 @default.
- W2205335144 cites W2004161699 @default.
- W2205335144 cites W2004454178 @default.
- W2205335144 cites W2004935593 @default.
- W2205335144 cites W2005149116 @default.
- W2205335144 cites W2005904599 @default.
- W2205335144 cites W2006327899 @default.
- W2205335144 cites W2007209007 @default.
- W2205335144 cites W2008714319 @default.
- W2205335144 cites W2011092379 @default.
- W2205335144 cites W2012271631 @default.
- W2205335144 cites W2013548901 @default.
- W2205335144 cites W2014366497 @default.
- W2205335144 cites W2014743618 @default.
- W2205335144 cites W2015658714 @default.
- W2205335144 cites W2015664999 @default.
- W2205335144 cites W2016304228 @default.
- W2205335144 cites W2016887263 @default.
- W2205335144 cites W2016993414 @default.
- W2205335144 cites W2017324840 @default.
- W2205335144 cites W2019280518 @default.
- W2205335144 cites W2020620764 @default.
- W2205335144 cites W2020841137 @default.
- W2205335144 cites W2021571036 @default.
- W2205335144 cites W2021628309 @default.
- W2205335144 cites W2022010765 @default.
- W2205335144 cites W2022093549 @default.