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- W2205584893 endingPage "4506" @default.
- W2205584893 startingPage "4491" @default.
- W2205584893 abstract "The Schiff base ligands benzylidene(4-tert-butylphenyl)amine 4-methyl ester (L1), (4-nitrobenzylidene)(4-tert-butylphenyl)amine (L2), and (4-cyanobenzylidene)(4-tert-butylphenyl)amine (L3) and the new series of cyclometalated mononuclear piano-stool complexes [(η5-C5Me5)RhCl(L1)] (1), [(η5-C5Me5)RhCl(L2)] (2), [(η5-C5Me5)RhCl(L3)] (3), [(η5-C5Me5)IrCl(L1)] (4), [(η5-C5Me5)IrCl(L2)] (5), and [(η5-C5Me5)IrCl(L3)] (6) have been synthesized. The ligands L1–L3 and complexes 1–6 have been thoroughly characterized by satisfactory elemental analyses, spectral studies (ESI-MS, IR, 1H and 13C NMR, UV–vis), and structures of 1–3 authenticated by X-ray single-crystal analyses. Efficient binding of 1–6 with calf thymus DNA (CT DNA) have been established by UV–vis and emission spectroscopic studies. Protein binding (bovine serum albumin, BSA) has been investigated by UV–vis, fluorescence, synchronous, and 3D fluorescence spectroscopy. Binding of the complexes with DNA through minor groove and hydrophobic interaction wi..." @default.
- W2205584893 created "2016-06-24" @default.
- W2205584893 creator A5006338900 @default.
- W2205584893 creator A5025365458 @default.
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- W2205584893 creator A5034434638 @default.
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- W2205584893 creator A5043450815 @default.
- W2205584893 creator A5058011193 @default.
- W2205584893 creator A5089296810 @default.
- W2205584893 date "2015-09-17" @default.
- W2205584893 modified "2023-10-14" @default.
- W2205584893 title "Synthesis, Structure, DNA/Protein Binding, and Anticancer Activity of Some Half-Sandwich Cyclometalated Rh(III) and Ir(III) Complexes" @default.
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