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• W2206460887 abstract "GRAPHICAL ABSTRACTS=o…s=o Interactions as a Driving Force for Low-Temperature Conformational Rearrangement of Stable H-Bonding {S(O)-Ch2-Ch2-OH···}2 Synthon in two Modifications of Diastereomeric Pinanyl Sulfoxides Co-CrystalAll authorsOlga A. Lodochnikova, Dmitry B. Krivolapov, Valeriya A. Startseva, Liliya E. Nikitina, Andrei V. Bodrov, Nadezhda P. Artemova, Vladimir V. Klochkov, Timur I. Madzhidov, Galina A. Chmutova & Igor A. Litvinovhttps://doi.org/10.1080/10426507.2015.1072185Published online:10 December 2015For the triclinic and monoclinic modifications of diastereomeric pinanyl sulfoxides co-crystal, remarkable alterations in unit cell parameters by transition from 293 to 150 К were ascertained. Such alterations are accompanied by conformational restructuring of a stable hydrogen-bonded synthon from an “unfolded” to a “folded” form. The driving force of this restructuring is the tendency to form S=O…S=O interactions, which show up in the low-temperature phases of both polymorphs. These are well-supported by the methods of quantum chemistry (DFT, B97-D/6-31G(d,p), AIM All)." @default.
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• W2206460887 date "2015-12-02" @default.
• W2206460887 modified "2023-09-24" @default.
• W2206460887 title "S=o…s=o Interactions as a Driving Force for Low-Temperature Conformational Rearrangement of Stable H-Bonding {S(O)-Ch2-Ch2-OH···}2 Synthon in two Modifications of Diastereomeric Pinanyl Sulfoxides Co-Crystal" @default.
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• W2206460887 doi "https://doi.org/10.1080/10426507.2015.1072185" @default.
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