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- W2206661597 abstract "Core/shell type carbon-coated Fe nanocapsules (Fe@C NCs) were in situ synthesized by DC arc-discharge plasma method in methane atmosphere. Such Fe nanocapsules have saturation magnetization of 29.32[Formula: see text]emu/g and specific surface area of 85.86[Formula: see text]m 2 /g. The carbon shell of Fe@C NCs was functionalized with oxygen-containing groups (such as –OH or –COOH) by using H 2 O 2 . The adsorption of organic dye, e.g., methylene blue (MB) was systematically investigated in different conditions, such as contact time, pH values and temperature. The maximum adsorption capacity (46.5[Formula: see text]mg/g) was calculated by fitting the adsorption isotherms with Langmuir model, coincident with the experimental result of 44.5[Formula: see text]mg/g. Kinetics data supported pseudo-second order model, and the thermodynamic process of adsorption was revealed as endothermic and spontaneous physisorption. The MB-absorbed Fe@C NCs can be entirely separated from the contaminative solution by a magnetic field and then successfully cycled for regeneration. After repetitive cycles of the adsorption/desorption experiments for five times, the removal efficiency can be maintained over 90%." @default.
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- W2206661597 date "2016-02-01" @default.
- W2206661597 modified "2023-10-17" @default.
- W2206661597 title "Novel in situ Synthesized Fe@C Magnetic Nanocapsules Used as Adsorbent for Removal of Organic Dyes and its Recycling" @default.
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- W2206661597 doi "https://doi.org/10.1142/s1793292016500132" @default.
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