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• W2207114037 abstract "Inexpensive and air stable triphenylcarbenium tetrafluoroborate efficiently promoted the carbofluorination of N-arylpropargylpyrrolidines bearing a tertiary allylic alcohol tether at the 2-position of the pyrrolidine ring to provide 1-isobutenyl-2-(fluoro(phenyl)methylenylhexahydro-1H-pyrrolizidines in a stereoselective fashion. When subjected to bis(trifluoromethane)sulfonamide, the same substrates underwent cycloisomerization reaction within minutes to generate 1-isobutenyl-2-benzoylhexahydro-1H-pyrrolizidines with excellent stereoselectivity." @default.
• W2207114037 created "2016-06-24" @default.
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• W2207114037 date "2015-10-16" @default.
• W2207114037 modified "2023-10-06" @default.
• W2207114037 title "Diastereoselective Synthesis of Fluorine-Containing Pyrrolizidines via Triphenylcarbenium Tetrafluoroborate-Promoted Carbofluorination of <i>N</i>-3-Arylpropargylpyrrolidine-Tethered Tertiary Allylic Alcohols" @default.
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• W2207114037 doi "https://doi.org/10.1021/acs.joc.5b02025" @default.
• W2207114037 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26458133" @default.
• W2207114037 hasPublicationYear "2015" @default.
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