Matches in SemOpenAlex for { <https://semopenalex.org/work/W2207130804> ?p ?o ?g. }
- W2207130804 endingPage "138" @default.
- W2207130804 startingPage "131" @default.
- W2207130804 abstract "The dynamics of polymer and filler in simplified industrial silica–styrene–butadiene nanocomposites (silica Zeosil 1165 MP, volume fraction 0–21%v) have been studied with broadband dielectric spectroscopy (BDS) and nuclear magnetic resonance (NMR). The fraction of graftable matrix chains was varied from 0 to 100%D3. The introduction of silica nanoparticles is shown to leave the segmental relaxation unaffected, an observation confirmed by the measurement of only a thin (some Angstroms thick) immobilized layer by NMR. The low-frequency measurements are resolved in two distinct dielectric Maxwell–Wagner–Sillars (MWS) processes of different behavior with respect to changes of large-scale silica structures induced by variations of filler fraction and grafting. It is found that increasing grafting leaves the first MWS-process unaffected, while it decreases the strength of the (slower) second MWS by about a decade. At constant silica volume fraction, this indicates depercolation of the filler, thereby providing a microscopic explanation of the evolution of rheological reinforcement. The sensitivity to large-scale reorganizations together with a characterization of local polymer dynamics provides insight over many length- and time-scales into structure and dynamics of nanocomposites, and thus the physical origin of the reinforcement effect." @default.
- W2207130804 created "2016-06-24" @default.
- W2207130804 creator A5013584939 @default.
- W2207130804 creator A5031663053 @default.
- W2207130804 creator A5043239750 @default.
- W2207130804 creator A5071484638 @default.
- W2207130804 creator A5085716031 @default.
- W2207130804 creator A5086240324 @default.
- W2207130804 date "2015-09-01" @default.
- W2207130804 modified "2023-10-17" @default.
- W2207130804 title "Depercolation of aggregates upon polymer grafting in simplified industrial nanocomposites studied with dielectric spectroscopy" @default.
- W2207130804 cites W1973093616 @default.
- W2207130804 cites W1974914236 @default.
- W2207130804 cites W1975843336 @default.
- W2207130804 cites W1977225912 @default.
- W2207130804 cites W1979254140 @default.
- W2207130804 cites W1982642249 @default.
- W2207130804 cites W1983260751 @default.
- W2207130804 cites W1988762454 @default.
- W2207130804 cites W1989107468 @default.
- W2207130804 cites W1990013345 @default.
- W2207130804 cites W1990469805 @default.
- W2207130804 cites W1991037488 @default.
- W2207130804 cites W1995183690 @default.
- W2207130804 cites W1996537429 @default.
- W2207130804 cites W2004471333 @default.
- W2207130804 cites W2007284174 @default.
- W2207130804 cites W2007304362 @default.
- W2207130804 cites W2015632637 @default.
- W2207130804 cites W2022529846 @default.
- W2207130804 cites W2027696247 @default.
- W2207130804 cites W2032592615 @default.
- W2207130804 cites W2036211101 @default.
- W2207130804 cites W2040578197 @default.
- W2207130804 cites W2044250060 @default.
- W2207130804 cites W2045137012 @default.
- W2207130804 cites W2049947813 @default.
- W2207130804 cites W2065127019 @default.
- W2207130804 cites W2073966596 @default.
- W2207130804 cites W2074539401 @default.
- W2207130804 cites W2076839813 @default.
- W2207130804 cites W2088551312 @default.
- W2207130804 cites W2106347793 @default.
- W2207130804 cites W2113108628 @default.
- W2207130804 cites W2117339135 @default.
- W2207130804 cites W2123790418 @default.
- W2207130804 cites W2128240782 @default.
- W2207130804 cites W2143113732 @default.
- W2207130804 cites W2157242092 @default.
- W2207130804 cites W2161534019 @default.
- W2207130804 cites W2168241859 @default.
- W2207130804 cites W2235454381 @default.
- W2207130804 cites W2313572046 @default.
- W2207130804 cites W2320512019 @default.
- W2207130804 cites W2322643392 @default.
- W2207130804 cites W2325806896 @default.
- W2207130804 cites W2328204475 @default.
- W2207130804 cites W3106109655 @default.
- W2207130804 cites W4206856024 @default.
- W2207130804 doi "https://doi.org/10.1016/j.polymer.2015.07.045" @default.
- W2207130804 hasPublicationYear "2015" @default.
- W2207130804 type Work @default.
- W2207130804 sameAs 2207130804 @default.
- W2207130804 citedByCount "32" @default.
- W2207130804 countsByYear W22071308042016 @default.
- W2207130804 countsByYear W22071308042017 @default.
- W2207130804 countsByYear W22071308042018 @default.
- W2207130804 countsByYear W22071308042019 @default.
- W2207130804 countsByYear W22071308042020 @default.
- W2207130804 countsByYear W22071308042021 @default.
- W2207130804 countsByYear W22071308042022 @default.
- W2207130804 countsByYear W22071308042023 @default.
- W2207130804 crossrefType "journal-article" @default.
- W2207130804 hasAuthorship W2207130804A5013584939 @default.
- W2207130804 hasAuthorship W2207130804A5031663053 @default.
- W2207130804 hasAuthorship W2207130804A5043239750 @default.
- W2207130804 hasAuthorship W2207130804A5071484638 @default.
- W2207130804 hasAuthorship W2207130804A5085716031 @default.
- W2207130804 hasAuthorship W2207130804A5086240324 @default.
- W2207130804 hasBestOaLocation W22071308044 @default.
- W2207130804 hasConcept C127413603 @default.
- W2207130804 hasConcept C133386390 @default.
- W2207130804 hasConcept C15744967 @default.
- W2207130804 hasConcept C159985019 @default.
- W2207130804 hasConcept C188027245 @default.
- W2207130804 hasConcept C192562407 @default.
- W2207130804 hasConcept C200990466 @default.
- W2207130804 hasConcept C2775937945 @default.
- W2207130804 hasConcept C2776029896 @default.
- W2207130804 hasConcept C2777973245 @default.
- W2207130804 hasConcept C3231350 @default.
- W2207130804 hasConcept C42360764 @default.
- W2207130804 hasConcept C49040817 @default.
- W2207130804 hasConcept C521977710 @default.
- W2207130804 hasConcept C65590680 @default.
- W2207130804 hasConcept C77805123 @default.
- W2207130804 hasConcept C92880739 @default.
- W2207130804 hasConceptScore W2207130804C127413603 @default.