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• W2209222421 abstract "Copper-based catalysts were prepared via ammonia evaporation co-precipitation method. Structure evolutions of the catalysts were systematically characterized by XRD, FTIR, TG, SEM, N2-physisorption, ICP-AES, N2O chemisorption and XPS focusing on the influence of promoters on the catalytic behavior in the hydrogenation of diethyl malonate to 1,3-propanediol. The results showed that diethyl malonate conversion and 1,3-propanediol selectivity could reach 96.71% and 29.76% respectively at 473 K with 2.0 MPa and 1.8 h− 1 with boron as promoter. The improved catalytic performance of Cu-B/SiO2 catalyst could be attributed to more Cu0 formed with the inhibition of copper phyllosilicate and better dispersion of copper species." @default.
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• W2209222421 date "2016-01-01" @default.
• W2209222421 modified "2023-10-16" @default.
• W2209222421 title "Effect of promoters on hydrogenation of diethyl malonate to 1,3-propanediol over nano copper-based catalysts" @default.
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• W2209222421 doi "https://doi.org/10.1016/j.catcom.2015.10.031" @default.
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