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- W220967691 abstract "X-ray crystal structural data at 100 (2) K for the thallium(I) complex of a fluorinated bis(pyrazolyl)borate, {bis[3,5-bis(trifluoromethyl)-1 H -pyrazol-1-yl-κ N 2 ]borato}thallium(I), [Tl(C 10 H 4 BF 12 N 4 )], abbreviated as [H 2 B{3,5-(CF 3 ) 2 pz} 2 ]Tl, and the related tris(pyrazolyl)borate, {tris[3,5-bis(trifluoromethyl)-1 H -pyrazol-1-yl-κ N 2 ]borato}thallium(I), [Tl(C 15 H 4 BF 18 N 6 )], abbreviated as [HB{3,5-(CF 3 ) 2 pz} 3 ]Tl, are reported. [H 2 B{3,5-(CF 3 ) 2 pz} 2 ]Tl features a two-coordinate Tl I atom with a bent geometry and a boat-shaped bis(pyrazolyl)borate ligand. It also has several additional inter- and intramolecular Tl...H and Tl...F contacts in the solid state. The tris(pyrazolyl)borate analogue [HB{3,5-(CF 3 ) 2 pz} 3 ]Tl has a trigonal–pyramidal thallium centre and features inter- and intramolecular Tl...F contacts." @default.
- W220967691 created "2016-06-24" @default.
- W220967691 creator A5018200496 @default.
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- W220967691 date "2013-08-03" @default.
- W220967691 modified "2023-09-23" @default.
- W220967691 title "Thallium(I) complexes of fluorinated bis- and tris(pyrazolyl)borate ligands: [H<sub>2</sub>B{3,5-(CF<sub>3</sub>)<sub>2</sub>pz}<sub>2</sub>]Tl and [HB{3,5-(CF<sub>3</sub>)<sub>2</sub>pz}<sub>3</sub>]Tl" @default.
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- W220967691 doi "https://doi.org/10.1107/s0108270113016612" @default.
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