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- W2211559182 endingPage "271" @default.
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- W2211559182 abstract "This chapter discusses the structures of main group organometallic compounds containing electron-deficient bridge bonds. Main group metals that form electron-deficient bridged molecules are those with low electronegativity and small size. The structures of substantial numbers of simple organoaluminum species have been reported during the past few years. The structures of several other symmetrical organoaluminum compounds––which have important implications with regard to electron-deficient bonding––have been determined from X-ray data. Cryoscopic and spectroscopic evidence has been used to show that trivinylgallium, unlike the alkylgallium derivatives, is dimeric in solution, thus lending credence to the suggestion. A second class of unsymmetrically bridged systems is represented by pentamethyl dialuminum in which the bridging atoms are different—one providing an electron-deficient bridge bond and the other a normal bridge with two electron bonds. For several mixed vinyl–hydride systems, on the basis of nuclear magnetic resonance (NMR) spectral studies, the species are dimeric with one hydrogen and one vinyl bridge. Both trimethylgallium and -indium are monomeric in solution, and structural studies on the trimethylindium and triphenylindium and triphenylgallium show that these species are not bridged dimeric molecules in the solid state. There are a substantial number of systems in which electron-deficient bridge bonds have been reported to occur among dissimilar metals." @default.
- W2211559182 created "2016-06-24" @default.
- W2211559182 creator A5043654905 @default.
- W2211559182 date "1977-01-01" @default.
- W2211559182 modified "2023-10-14" @default.
- W2211559182 title "Structures of Main Group Organometallic Compounds Containing Electron-Deficient Bridge Bonds" @default.
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