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- W2212071105 abstract "The oxidative addition reaction of bis(4′,5′-di-methoxybenzo-)-1,2,5,6-tetrathiocin (1) to zero-valent Pt(PPh3)4 under microwave irradiation for 30 min afforded a mixture of the title Pt(II) complexes, (dmobdt)Pt(PPh3)2 (2) and [(dmobdt)Pt(PPh3)]2 (3) [dmobdt2− = 4,5-dimethoxybenzene-1,2-dithiolate]. Under extended reaction times the dimetallic complex 3 was isolated as the exclusive Pt-containing product indicating 2 is an intermediate en route to 3. The structures of 1–3 have been determined by X-ray diffraction." @default.
- W2212071105 created "2016-06-24" @default.
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- W2212071105 date "2016-03-01" @default.
- W2212071105 modified "2023-09-26" @default.
- W2212071105 title "Oxidative addition of bis-(dimethoxybenzo)-1,2,5,6-tetrathiocins to Pt(PPh3)4: Synthesis and structures of mono- and di-metallic platinum dithiolate complexes, (dmobdt)Pt(PPh3)2 and [(dmobdt)Pt(PPh3)]2" @default.
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- W2212071105 doi "https://doi.org/10.1016/j.poly.2015.09.049" @default.
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