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- W2213108754 abstract "The title compound, C 11 H 13 NO 6 , exhibits an intramolecular O–H...O=C hydrogen bond between the N -hydroxyl H atom and carbonyl O atom of the neighboring acetyl group. This finding contradicts a previously published model in which the hydrogen bond was postulated to occur with the neighboring carbomethoxy group. This relatively strong hydrogen bond [O—H...O: D = 2.5583 (11) Å and θ = 152°] may underlie the resistance of the title compound to oxidation into the corresponding nitroxide." @default.
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- W2213108754 date "2014-01-04" @default.
- W2213108754 modified "2023-09-26" @default.
- W2213108754 title "Dimethyl 5-acetyl-1-hydroxy-4-methyl-1H-pyrrole-2,3-dicarboxylate, an oxidation-resistantN-hydroxypyrrole" @default.
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- W2213108754 doi "https://doi.org/10.1107/s1600536813034466" @default.
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