FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2213156623> ?p ?o ?g. }

• W2213156623 endingPage "725" @default.
• W2213156623 startingPage "716" @default.
• W2213156623 abstract "To achieve complete oxidation of ethanol (EOR) to CO2, higher operating temperatures (often called intermediate-T, 150-200 °C) and appropriate catalysts are required. We examine here titanium oxycarbide (hereafter TiOxCy) as a possible alternative to standard carbon-based supports to enhance the stability of the catalyst/support assembly at intermediate-T. To test this material as electrocatalyst support, a systematic study of its behavior under electrochemical conditions was carried out. To have a clear description of the chemical changes of TiOxCy induced by electrochemical polarization of the material, a special setup that allows the combination of X-ray photoelectron spectroscopy and electrochemical measurements was used. Subsequently, an electrochemical study was carried out on TiOxCy powders, both at room temperature and at 150 °C. The present study has revealed that TiOxCy is a sufficiently conductive material whose surface is passivated by a TiO2 film under working conditions, which prevents the full oxidation of the TiOxCy and can thus be considered a stable electrode material for EOR working conditions. This result has also been confirmed through density functional theory (DFT) calculations on a simplified model system. Furthermore, it has been experimentally observed that ethanol molecules adsorb on the TiOxCy surface, inhibiting its oxidation. This result has been confirmed by using in situ Fourier transform infrared spectroscopy (FTIRS). The adsorption of ethanol is expected to favor the EOR in the presence of suitable catalyst nanoparticles supported on TiOxCy." @default.
• W2213156623 created "2016-06-24" @default.
• W2213156623 creator A5016845262 @default.
• W2213156623 creator A5018190831 @default.
• W2213156623 creator A5019209672 @default.
• W2213156623 creator A5021025452 @default.
• W2213156623 creator A5023100324 @default.
• W2213156623 creator A5024009447 @default.
• W2213156623 creator A5030507498 @default.
• W2213156623 creator A5038183338 @default.
• W2213156623 creator A5038557702 @default.
• W2213156623 creator A5060514693 @default.
• W2213156623 creator A5069693898 @default.
• W2213156623 creator A5079650151 @default.
• W2213156623 creator A5084399285 @default.
• W2213156623 date "2015-12-28" @default.
• W2213156623 modified "2023-10-18" @default.
• W2213156623 title "Electrochemical Behavior of TiO_<i>x</i>C_<i>y</i> as Catalyst Support for Direct Ethanol Fuel Cells at Intermediate Temperature: From Planar Systems to Powders" @default.
• W2213156623 cites W115327513 @default.
• W2213156623 cites W1775976028 @default.
• W2213156623 cites W1967711993 @default.
• W2213156623 cites W1970735107 @default.
• W2213156623 cites W1975905088 @default.
• W2213156623 cites W1977287462 @default.
• W2213156623 cites W1983498305 @default.
• W2213156623 cites W1983671034 @default.
• W2213156623 cites W1985070049 @default.
• W2213156623 cites W1998719903 @default.
• W2213156623 cites W2004973426 @default.
• W2213156623 cites W2005096199 @default.
• W2213156623 cites W2005138915 @default.
• W2213156623 cites W2009873085 @default.
• W2213156623 cites W2019565850 @default.
• W2213156623 cites W2022874142 @default.
• W2213156623 cites W2038070019 @default.
• W2213156623 cites W2043191056 @default.
• W2213156623 cites W2043468966 @default.
• W2213156623 cites W2051014978 @default.
• W2213156623 cites W2053655516 @default.
• W2213156623 cites W2053840213 @default.
• W2213156623 cites W2064977138 @default.
• W2213156623 cites W2071231146 @default.
• W2213156623 cites W2072859685 @default.
• W2213156623 cites W2074101524 @default.
• W2213156623 cites W2075626286 @default.
• W2213156623 cites W2080001307 @default.
• W2213156623 cites W2090307092 @default.
• W2213156623 cites W2091634275 @default.
• W2213156623 cites W2096098515 @default.
• W2213156623 cites W2100252608 @default.
• W2213156623 cites W2127891091 @default.
• W2213156623 cites W2167035995 @default.
• W2213156623 cites W2318836581 @default.
• W2213156623 cites W2321600982 @default.
• W2213156623 cites W2324415771 @default.
• W2213156623 cites W2324501842 @default.
• W2213156623 doi "https://doi.org/10.1021/acsami.5b09861" @default.
• W2213156623 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26674375" @default.
• W2213156623 hasPublicationYear "2015" @default.
• W2213156623 type Work @default.
• W2213156623 sameAs 2213156623 @default.
• W2213156623 citedByCount "29" @default.
• W2213156623 countsByYear W22131566232016 @default.
• W2213156623 countsByYear W22131566232017 @default.
• W2213156623 countsByYear W22131566232018 @default.
• W2213156623 countsByYear W22131566232019 @default.
• W2213156623 countsByYear W22131566232020 @default.
• W2213156623 countsByYear W22131566232021 @default.
• W2213156623 countsByYear W22131566232022 @default.
• W2213156623 countsByYear W22131566232023 @default.
• W2213156623 crossrefType "journal-article" @default.
• W2213156623 hasAuthorship W2213156623A5016845262 @default.
• W2213156623 hasAuthorship W2213156623A5018190831 @default.
• W2213156623 hasAuthorship W2213156623A5019209672 @default.
• W2213156623 hasAuthorship W2213156623A5021025452 @default.
• W2213156623 hasAuthorship W2213156623A5023100324 @default.
• W2213156623 hasAuthorship W2213156623A5024009447 @default.
• W2213156623 hasAuthorship W2213156623A5030507498 @default.
• W2213156623 hasAuthorship W2213156623A5038183338 @default.
• W2213156623 hasAuthorship W2213156623A5038557702 @default.
• W2213156623 hasAuthorship W2213156623A5060514693 @default.
• W2213156623 hasAuthorship W2213156623A5069693898 @default.
• W2213156623 hasAuthorship W2213156623A5079650151 @default.
• W2213156623 hasAuthorship W2213156623A5084399285 @default.
• W2213156623 hasConcept C127413603 @default.
• W2213156623 hasConcept C147789679 @default.
• W2213156623 hasConcept C150394285 @default.
• W2213156623 hasConcept C155672457 @default.
• W2213156623 hasConcept C160892712 @default.
• W2213156623 hasConcept C161790260 @default.
• W2213156623 hasConcept C171250308 @default.
• W2213156623 hasConcept C17525397 @default.
• W2213156623 hasConcept C175708663 @default.
• W2213156623 hasConcept C178790620 @default.
• W2213156623 hasConcept C179104552 @default.
• W2213156623 hasConcept C185592680 @default.
• W2213156623 hasConcept C191897082 @default.
• W2213156623 hasConcept C192562407 @default.

• next