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- W2214804544 abstract "We report on the preparation and electrochemical characterization of Li2M(SO4)2 (M = Co, Fe), where the Fe-based phase was previously unknown. Both compounds can be made at low temperatures (< 320 °C) and the Fe-based phase displays an open circuit voltage of 3.83 V vs. Li+/Li0 for the Fe3+/Fe2+ redox potential. This corresponds to the highest voltage ever obtained for the Fe3+/Fe2+ redox couple in an iron-based, fluorine-free compound and is only matched by the triplite phase of LiFeSO4F. While the theoretical capacity of 102 mA h g− 1 will likely limit the commercial prospects for this phase, knowledge of the structure will provide useful insight into the structural origin of these increased potentials." @default.
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- W2214804544 date "2012-07-01" @default.
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- W2214804544 title "Li2Fe(SO4)2 as a 3.83V positive electrode material" @default.
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- W2214804544 doi "https://doi.org/10.1016/j.elecom.2012.04.027" @default.
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