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• W2214976434 abstract "The first asymmetric cycloaddition of nonstabilized azomethine ylide and N-sulfinylimines is presented. In reactions with aryl–alkyl and heteroaryl–alkyl ketimines, excellent diastereoselectivities and good yields are obtained in all cases, regardless of the electronic character of the substituents at the aromatic rings. Moreover, the cycloadducts obtained can easily be deprotected in acid media, giving access to free 1,2-diamines which are prevalent in many natural and pharmaceutical products." @default.
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• W2214976434 date "2015-12-14" @default.
• W2214976434 modified "2023-10-15" @default.
• W2214976434 title "Asymmetric Synthesis of 1,2-Diamines bearing Tetrasubstituted Centers from Nonstabilized Azomethine Ylides and <i>N</i>-Sulfinylketimines under Brønsted Acid Catalysis" @default.
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• W2214976434 doi "https://doi.org/10.1021/acs.orglett.5b03251" @default.
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