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- W2215126134 abstract "A general thermodynamic treatment of adsorption from mixed solvents is provided. It is designed to apply in situations where adsorbed species may be regarded as distinct from their bulk counterparts. Clausius-Clapeyron type expressions are derived which relate differential and integral enthalpies of adsorption to the temperature dependence of the adsorption equilibria concerned. The differential enthalpies refer to the transfer of material from bulk to adsorbed states under the condition that non-specifically adsorbed material is allowed to re-equilibrate. The integral enthalpies refer to the enthalpy of formation of the interface from the bulk solution at constant interfacial and bulk intensive properties. They correspond closely to heats obtainable from calorimetric measurements. The treatment is applied to the adsorption of a nonionic surfactant from a binary mixture and to the adsorption of anionic surfactant from an electrolyte solution with a commonion." @default.
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- W2215126134 date "1983-01-01" @default.
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- W2215126134 title "THERMODYNAMICS OF ADSORPTION FROM MIXED SOLVENTS" @default.
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- W2215126134 doi "https://doi.org/10.1016/b978-0-12-530980-6.50007-3" @default.
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