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• W2217307100 endingPage "83" @default.
• W2217307100 startingPage "23" @default.
• W2217307100 abstract "YBa2Cu3C6+x is perhaps the most heavily studied compound among the superconducting cuprates. Since its discovery in 19871, thousands of scientific papers, describing studies on this compound, have been published. One of the reasons is that this compound, due to the high Tc (93 K), the relatively simple synthesis route, and the very good intrinsic superconducting behavior in an applied field, has been viewed as being promising for practical applications. Also, YBa2Cu3O6+x became the aristotype of a family of compounds with the same basic structure, obtained by substitutions of one or more ionic species, which allowed the effect of ionic sizes, point and extended defects etc. to be explored in detail. From the structural point of view, one of the most interesting properties of this compound is its ability to support a large oxygen non-stoichiometry. In fact, its oxygen content can be varied from six (x=0) to seven (x=l) in a continuous way The maximum critical temperature is achieved close to the highest oxygen content. The oxygen non-stoichiometry occurs in the so-called basal plane, which contains copper and oxygen atoms and acts as a “charge reservoir” for the CuO2 double layer, where superconductivity primarily occurs. As new families of superconducting copper oxides were discovered over the years, it has become increasingly clear that, due to this specific structural features, YBa2Cu3O6+x is far from being a typical compound, and that it possesses a number of peculiarities, including the complex self-doping mechanism associated with oxygen ordering in the basal plane." @default.
• W2217307100 created "2016-06-24" @default.
• W2217307100 creator A5038682831 @default.
• W2217307100 date "1998-01-01" @default.
• W2217307100 modified "2023-09-27" @default.
• W2217307100 title "Structural Anomalies, Oxygen Ordering and Superconductivity in YBa2Cu3O6+x" @default.
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