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• W2217361036 abstract "Consideration of the role of dynamic trajectories in [1,2]- and [2,3]-sigmatropic rearrangements suggests a counterintuitive approach to controlling the selectivity. In our hypothesis, [2,3] selectivity can be promoted by reaction conditions that thermodynamically disfavor the [2,3] rearrangement step and thereby make the transition state later. The application of this idea has led to a successful prescription for dictating the selectivity in Stevens/Sommelet-Hauser rearrangements of ammonium ylides. A combination of kinetic isotope effects, crossover experiments, and computational dynamic trajectories support the idea that the selectivity is controlled through control of the path of trajectories." @default.
• W2217361036 created "2016-06-24" @default.
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• W2217361036 date "2015-11-10" @default.
• W2217361036 modified "2023-10-14" @default.
• W2217361036 title "Controlling Selectivity by Controlling the Path of Trajectories" @default.
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• W2217361036 doi "https://doi.org/10.1021/jacs.5b08635" @default.
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