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- W2220329998 abstract "A knowledge of the entropy of adsorption, and hence the entropy of the adsorbed material, gives some indication of the extent t o which the molecules are capable of unhindered translation on the surface. Physical adsorption, although generally giving rise to mobile adsorption, may also under certain circumstances lead to localized adsorption. The smaller the heat of adsorption in relation to the heat of vaporisation, the greater is the probability of finding complete two-dimensional translational freedom. The lower the temperature at which the adsorption is carried out, the more likely is the adsorption to be of the immobile type. Symmetry of the adsorbate molecules is important to a certain extent, especially with the larger molecules, for example, CC14, and ethyl alcohol have considerable freedom on silica gel and mercury respectively, but butyl alcohol and toluene do not. The chapter examines the three cases of chemisorptions that show localized adsorption, but there may be other examples in which a considerable mobility is possessed by the adsorbed molecules or atoms. Entropy values can give indications of dissociation or, more particularly, of association when localized adsorption takes place. This is clearly noticeable in the values for the entropy of water on mercury." @default.
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- W2220329998 date "1950-01-01" @default.
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- W2220329998 title "Entropy of Adsorption" @default.
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