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- W2220440015 abstract "It had been previously shown that the presence of S/sup 3//sup 5/ (E/sub m//sub a//sub x/= 0-167 Mev) in a MgSO/sub 4/ catalyst improved the yield in the dehydration of cyclohexanol. The introduction of Ca/sup 4//sup 5/ (E/sub m//sub a//sub x/= 0-254 Mev) as CaCl/sub 2/ to MgSO/sub 4/ resulted in a rise of catalytic activity in all cases, although pure CaCl/sub 2/, even with a high content of Ca (93.7 mc/g), is inert as a catalyst. The increase in the degree of conversion at a given temperature was found to depend linearly on the log of the radiation dose imparted to the catalyst by S/sup 3//sup 5/or Ca/sup 4//sup 5/. Excitation of the cathlyst by bombardment with beta particles improves the kinetics of the process. The apparent activation energy is decreased with the use of radioactive catalysts. (TTT)" @default.
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- W2220440015 date "1961-03-21" @default.
- W2220440015 modified "2023-09-26" @default.
- W2220440015 title "RADIOACTIVE CATALYSTS. THE DEHYDRATION OF CYCLOHEXANOL WITH A MIXTURE OF MAGNESIUM SULFATE AND CALCIUM CHLORIDE AS A CATALYST" @default.
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