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• W2220615167 abstract "An expert and easy one-step catalytic method for the multi O–C coupling of alkyne is developed for the synthesis of valuable α-ketoesters and their chiral analogues, in contrast to the generation of esters by a noncatalytic method. The in situ generated powerful AgII catalyst from AgOTf is the workhorse in the oxidative grafting of alkyne with PhIO and alcohol. The radical mechanism is confirmed in our controlled experiments and UV–vis study." @default.
• W2220615167 created "2016-06-24" @default.
• W2220615167 creator A5016277469 @default.
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• W2220615167 date "2015-12-14" @default.
• W2220615167 modified "2023-09-27" @default.
• W2220615167 title "In Situ Generated Ag^II-Catalyzed Selective Oxo-Esterification of Alkyne with Alcohol to α-Ketoester: Photophysical Study" @default.
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• W2220615167 doi "https://doi.org/10.1021/acs.orglett.5b03484" @default.
• W2220615167 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26651877" @default.
• W2220615167 hasPublicationYear "2015" @default.
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