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- W2220687110 endingPage "595" @default.
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- W2220687110 abstract "Interaction of isomeric 4-nitro- or 3-nitrophthalonitrile with triethyl phosphonoacetate, diethyl cyanomethylphosphonate or tetraethyl methylenediphosphonate in basic conditions resulted in regioselective C -nucleophilic oxidative substitution of hydrogen ortho-located to nitro group, new phthalonitriles with diethoxyphosphorylmethyl or bis(diethoxyphosphoryl)methyl group were isolated in modest yields. In the same conditions one chlorine atom of tetrachlorophthalonitrile was regioselectively substituted with triethyl phosphonoacetate. In basic conditions, both parent phthalonitriles and corresponding zinc phthalocyanines with ortho-located nitro and diethoxyphosphoryl substituted methyl groups are involved in reversible acid-base interaction accompanied with large bathochromic shift of their long wavelength absorption maxima in visible or NIR region, correspondingly. Formation of tetraazachlorin- and tetraaza(iso)bacteriochlorin-like anions is proposed for explanation of this unprecedent bathochromic shift for phthalocyanines." @default.
- W2220687110 created "2016-06-24" @default.
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- W2220687110 date "2013-06-01" @default.
- W2220687110 modified "2023-09-23" @default.
- W2220687110 title "Phthalocyanines with phosphonate moiety <i>via</i><font>C</font>-nucleophilic substitution in phthalonitriles" @default.
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- W2220687110 doi "https://doi.org/10.1142/s108842461350051x" @default.
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