Matches in SemOpenAlex for { <https://semopenalex.org/work/W2221320265> ?p ?o ?g. }
- W2221320265 endingPage "658" @default.
- W2221320265 startingPage "654" @default.
- W2221320265 abstract "Molecules that are mirror images of each other usually behave identically, unless they are interacting with other chiral objects. High-harmonic generation can provide access to the dynamics of chiral interactions on ultrafast timescales. Chiral molecules that are non-superimposable mirror images of each other, known as enantiomers, have identical chemical and physical properties unless they interact with another chiral entity, such as chiral light. Chiroptical1 effects arising from such interactions are used to detect enantiomers in mixtures and to induce enantioselective synthesis and catalysis. Chiroptical effects often arise from the interplay between light-induced electric- and magnetic-dipole transitions in a molecule and evolve on ultrafast electronic timescales. Here we use high-harmonic generation2,3 from a randomly oriented gas of molecules subjected to an intense laser field, to probe chiral interactions on these sub-femtosecond timescales. We show that a slight disparity in the laser-driven electron dynamics in the two enantiomers is recorded and amplified by several orders of magnitude in the harmonic spectra. Our work shows that chiroptical detection can go beyond detecting chiral structure4,5,6,7 to resolving and controlling chiral dynamics on electronic timescales." @default.
- W2221320265 created "2016-06-24" @default.
- W2221320265 creator A5001185754 @default.
- W2221320265 creator A5001984629 @default.
- W2221320265 creator A5003420285 @default.
- W2221320265 creator A5015817532 @default.
- W2221320265 creator A5019643423 @default.
- W2221320265 creator A5022767786 @default.
- W2221320265 creator A5028725280 @default.
- W2221320265 creator A5032818418 @default.
- W2221320265 creator A5034587597 @default.
- W2221320265 creator A5037126566 @default.
- W2221320265 creator A5037537996 @default.
- W2221320265 creator A5042740712 @default.
- W2221320265 creator A5045495552 @default.
- W2221320265 creator A5053800445 @default.
- W2221320265 creator A5058412723 @default.
- W2221320265 creator A5061020333 @default.
- W2221320265 creator A5063348099 @default.
- W2221320265 creator A5084024220 @default.
- W2221320265 creator A5088189241 @default.
- W2221320265 creator A5089738851 @default.
- W2221320265 date "2015-06-29" @default.
- W2221320265 modified "2023-10-16" @default.
- W2221320265 title "Probing molecular chirality on a sub-femtosecond timescale" @default.
- W2221320265 cites W1571933582 @default.
- W2221320265 cites W1963751377 @default.
- W2221320265 cites W1972433388 @default.
- W2221320265 cites W1973010435 @default.
- W2221320265 cites W1975688133 @default.
- W2221320265 cites W1988999358 @default.
- W2221320265 cites W1991771185 @default.
- W2221320265 cites W1993511231 @default.
- W2221320265 cites W2008631799 @default.
- W2221320265 cites W2023763841 @default.
- W2221320265 cites W2024125608 @default.
- W2221320265 cites W2033499264 @default.
- W2221320265 cites W2033999476 @default.
- W2221320265 cites W2035188058 @default.
- W2221320265 cites W2038736839 @default.
- W2221320265 cites W2043996318 @default.
- W2221320265 cites W2044223171 @default.
- W2221320265 cites W2053633298 @default.
- W2221320265 cites W2054260243 @default.
- W2221320265 cites W2055746702 @default.
- W2221320265 cites W2056628333 @default.
- W2221320265 cites W2059520593 @default.
- W2221320265 cites W2061382044 @default.
- W2221320265 cites W2062099808 @default.
- W2221320265 cites W2067435087 @default.
- W2221320265 cites W2068599440 @default.
- W2221320265 cites W2069141896 @default.
- W2221320265 cites W2074836554 @default.
- W2221320265 cites W2074927834 @default.
- W2221320265 cites W2078330413 @default.
- W2221320265 cites W2078609090 @default.
- W2221320265 cites W2085230836 @default.
- W2221320265 cites W2087990864 @default.
- W2221320265 cites W2091510035 @default.
- W2221320265 cites W2093889451 @default.
- W2221320265 cites W2094177521 @default.
- W2221320265 cites W2112480597 @default.
- W2221320265 cites W2171839036 @default.
- W2221320265 cites W2320415643 @default.
- W2221320265 cites W2495346592 @default.
- W2221320265 doi "https://doi.org/10.1038/nphys3369" @default.
- W2221320265 hasPublicationYear "2015" @default.
- W2221320265 type Work @default.
- W2221320265 sameAs 2221320265 @default.
- W2221320265 citedByCount "205" @default.
- W2221320265 countsByYear W22213202652015 @default.
- W2221320265 countsByYear W22213202652016 @default.
- W2221320265 countsByYear W22213202652017 @default.
- W2221320265 countsByYear W22213202652018 @default.
- W2221320265 countsByYear W22213202652019 @default.
- W2221320265 countsByYear W22213202652020 @default.
- W2221320265 countsByYear W22213202652021 @default.
- W2221320265 countsByYear W22213202652022 @default.
- W2221320265 countsByYear W22213202652023 @default.
- W2221320265 crossrefType "journal-article" @default.
- W2221320265 hasAuthorship W2221320265A5001185754 @default.
- W2221320265 hasAuthorship W2221320265A5001984629 @default.
- W2221320265 hasAuthorship W2221320265A5003420285 @default.
- W2221320265 hasAuthorship W2221320265A5015817532 @default.
- W2221320265 hasAuthorship W2221320265A5019643423 @default.
- W2221320265 hasAuthorship W2221320265A5022767786 @default.
- W2221320265 hasAuthorship W2221320265A5028725280 @default.
- W2221320265 hasAuthorship W2221320265A5032818418 @default.
- W2221320265 hasAuthorship W2221320265A5034587597 @default.
- W2221320265 hasAuthorship W2221320265A5037126566 @default.
- W2221320265 hasAuthorship W2221320265A5037537996 @default.
- W2221320265 hasAuthorship W2221320265A5042740712 @default.
- W2221320265 hasAuthorship W2221320265A5045495552 @default.
- W2221320265 hasAuthorship W2221320265A5053800445 @default.
- W2221320265 hasAuthorship W2221320265A5058412723 @default.
- W2221320265 hasAuthorship W2221320265A5061020333 @default.
- W2221320265 hasAuthorship W2221320265A5063348099 @default.
- W2221320265 hasAuthorship W2221320265A5084024220 @default.