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- W2222367675 abstract "In the title binuclear complex, [Fe(2)(C(8)H(7)O(2))(4)(C(12)H(8)N(2))(2)(H(2)O)], the Fe(II) ion is six-coordinated by three carboxylate O atoms from three 4-methyl-benzoate ligands, two N atoms from two 1,10-phenanthroline ligands and one bridging aqua ligand in a distorted octa-hedral geometry. The coordinated water mol-ecule acting as the bridging ligand is located on a twofold axes and the complex mol-ecule displays C(2) mol-ecular symmetry. The Fe⋯Fe separation in the binuclear complex is 3.490 (3) Å. The crystal structure is stabilized by hydrogen bonding and π-π stacking inter-actions [the centroid-centroid distance between adjacent 1,10-phenanthroline ring systems is 3.653 (2) Å, and that between the 1,10-phenanthroline ring system and the phenyl ring of the 4-methyl-benzoate unit of a neighbouring complex is 3.622 (3) Å]." @default.
- W2222367675 created "2016-06-24" @default.
- W2222367675 creator A5036605276 @default.
- W2222367675 date "2008-05-17" @default.
- W2222367675 modified "2023-10-17" @default.
- W2222367675 title "μ-Aqua-bis(μ-4-methylbenzoato-κ<sup>2</sup><i>O</i>:<i>O</i>′)bis[(4-methylbenzoato-κ<i>O</i>)(1,10-phenanthroline-κ<sup>2</sup><i>N</i>,<i>N</i>′)iron(II)]" @default.
- W2222367675 cites W2131350133 @default.
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- W2222367675 doi "https://doi.org/10.1107/s1600536808014207" @default.
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