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- W2224964900 abstract "The title compound, [Na(2)(C(10)H(16)Cl(3)N(3)O(4)P)(2)(H(2)O)(2)](n), can be considered as a two-dimensional coordination polymer in which one-dimensional chains are connected to each other by inter-molecular C-H⋯O hydrogen bonds involving the water mol-ecules. The Na(I) ion is five-coordinated in a distorted trigonal-bipyramidal geometry. The connection between the two Na(I) ions is facilitated by the two μ-O atoms of the carbonyl group of the 2,2,2-trichloro-N-(dimorpholino-phosphor-yl)acetamide (CAPh) ligand. A bridging coordination of the CAPh ligand via the carbonyl O atom is observed for the first time. The bridging water mol-ecules form inter-molecular O-H⋯O hydrogen bonds with the O atoms of the morpholine rings and the phosphoryl groups of neighboring CAPh mol-ecules." @default.
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- W2224964900 date "2010-03-20" @default.
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- W2224964900 title "<i>catena</i>-Poly[sodium-di-μ-aqua-sodium-bis[μ-2,2,2-trichloro-<i>N</i>-(dimorpholinophosphoryl)acetamide]]" @default.
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- W2224964900 doi "https://doi.org/10.1107/s1600536810009670" @default.
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