FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2225765013> ?p ?o ?g. }

• W2225765013 endingPage "78" @default.
• W2225765013 startingPage "71" @default.
• W2225765013 abstract "The photoredox catalysis applied to the field of polymers and more particularly to the design of photoinitiating systems is briefly reviewed. Two novel phenylisoquinoline-based iridium complexes with fluorine substituents (bis[5-fluoro-2-(1-isoquinolinyl-κN)phenyl-κC](2,2,6,6-tetramethyl-3,5-heptanedionato-κO3,κO5)-iridium (III) (Ir_b) and bis[3,5-difluoro-2-(1-isoquinolinyl-κN)phenyl-κC](2,2,6,6-tetramethyl-3,5-heptanedionato-κO3,κO5)-iridium (III) (Ir_c) are proposed as photoredox catalysts (also called photoinitiator catalysts) and incorporated into suitable photoinitiating systems for cationic and radical polymerization. (3,4-Epoxycyclohexane)methyl-3,4-epoxycyclohexylcarboxylate (EPOX) and trimethylolpropane triacrylate (TMPTA) were used as benchmark monomers for cationic and radical photopolymerization. These new catalysts are compared to our very recently proposed unsubstituted catalyst compound: bis[2-(1-isoquinolinyl-κN)phenyl-κC](2,2,6,6-tetramethyl-3,5-heptanedionato-κO3,κO5)-iridium (III) (Ir_a). Remarkably, these catalysts exhibit improved light absorption properties and are characterized by a panchromatic behavior which ensures the photosensitivity of the polymerizable films to blue, green and red lights. The photochemical properties as well as the chemical mechanisms associated with these catalysts are investigated by ESR spin-trapping, laser flash photolysis, steady state photolysis, cyclic voltammetry and luminescence experiments. The structure/reactivity relationships as well as the substitution effect (by the fluorine) are discussed." @default.
• W2225765013 created "2016-06-24" @default.
• W2225765013 creator A5003755520 @default.
• W2225765013 creator A5008288265 @default.
• W2225765013 creator A5028723908 @default.
• W2225765013 creator A5031287643 @default.
• W2225765013 creator A5051277424 @default.
• W2225765013 creator A5076071968 @default.
• W2225765013 date "2016-01-01" @default.
• W2225765013 modified "2023-09-24" @default.
• W2225765013 title "Photoredox process induced polymerization reactions: Iridium complexes for panchromatic photoinitiating systems" @default.
• W2225765013 cites W142358202 @default.
• W2225765013 cites W1941587239 @default.
• W2225765013 cites W1991171003 @default.
• W2225765013 cites W1992057796 @default.
• W2225765013 cites W1994179009 @default.
• W2225765013 cites W1996259344 @default.
• W2225765013 cites W1998081478 @default.
• W2225765013 cites W2017685895 @default.
• W2225765013 cites W2026134775 @default.
• W2225765013 cites W2027428451 @default.
• W2225765013 cites W2027759296 @default.
• W2225765013 cites W2029253088 @default.
• W2225765013 cites W2032065892 @default.
• W2225765013 cites W2036334433 @default.
• W2225765013 cites W2037313749 @default.
• W2225765013 cites W2044653429 @default.
• W2225765013 cites W2050379798 @default.
• W2225765013 cites W2051822378 @default.
• W2225765013 cites W2057873420 @default.
• W2225765013 cites W2058404230 @default.
• W2225765013 cites W2059192937 @default.
• W2225765013 cites W2081380246 @default.
• W2225765013 cites W2090187595 @default.
• W2225765013 cites W2090724481 @default.
• W2225765013 cites W2093527245 @default.
• W2225765013 cites W2095287593 @default.
• W2225765013 cites W2109856703 @default.
• W2225765013 cites W2136322731 @default.
• W2225765013 cites W2141509688 @default.
• W2225765013 cites W2144929531 @default.
• W2225765013 cites W2145773666 @default.
• W2225765013 cites W2150953134 @default.
• W2225765013 cites W2151665469 @default.
• W2225765013 cites W2154548550 @default.
• W2225765013 cites W2167820411 @default.
• W2225765013 cites W2168849722 @default.
• W2225765013 cites W2319182059 @default.
• W2225765013 cites W2320194542 @default.
• W2225765013 cites W2327931957 @default.
• W2225765013 cites W2329085673 @default.
• W2225765013 doi "https://doi.org/10.1016/j.crci.2015.06.016" @default.
• W2225765013 hasPublicationYear "2016" @default.
• W2225765013 type Work @default.
• W2225765013 sameAs 2225765013 @default.
• W2225765013 citedByCount "47" @default.
• W2225765013 countsByYear W22257650132016 @default.
• W2225765013 countsByYear W22257650132017 @default.
• W2225765013 countsByYear W22257650132018 @default.
• W2225765013 countsByYear W22257650132019 @default.
• W2225765013 countsByYear W22257650132020 @default.
• W2225765013 countsByYear W22257650132021 @default.
• W2225765013 countsByYear W22257650132022 @default.
• W2225765013 countsByYear W22257650132023 @default.
• W2225765013 crossrefType "journal-article" @default.
• W2225765013 hasAuthorship W2225765013A5003755520 @default.
• W2225765013 hasAuthorship W2225765013A5008288265 @default.
• W2225765013 hasAuthorship W2225765013A5028723908 @default.
• W2225765013 hasAuthorship W2225765013A5031287643 @default.
• W2225765013 hasAuthorship W2225765013A5051277424 @default.
• W2225765013 hasAuthorship W2225765013A5076071968 @default.
• W2225765013 hasBestOaLocation W22257650131 @default.
• W2225765013 hasConcept C121332964 @default.
• W2225765013 hasConcept C13472781 @default.
• W2225765013 hasConcept C148898269 @default.
• W2225765013 hasConcept C15487406 @default.
• W2225765013 hasConcept C161790260 @default.
• W2225765013 hasConcept C166940927 @default.
• W2225765013 hasConcept C178790620 @default.
• W2225765013 hasConcept C183882617 @default.
• W2225765013 hasConcept C185592680 @default.
• W2225765013 hasConcept C188027245 @default.
• W2225765013 hasConcept C2780634384 @default.
• W2225765013 hasConcept C44228677 @default.
• W2225765013 hasConcept C45849291 @default.
• W2225765013 hasConcept C521977710 @default.
• W2225765013 hasConcept C528581852 @default.
• W2225765013 hasConcept C62520636 @default.
• W2225765013 hasConcept C65165184 @default.
• W2225765013 hasConcept C75473681 @default.
• W2225765013 hasConcept C93391505 @default.
• W2225765013 hasConceptScore W2225765013C121332964 @default.
• W2225765013 hasConceptScore W2225765013C13472781 @default.
• W2225765013 hasConceptScore W2225765013C148898269 @default.
• W2225765013 hasConceptScore W2225765013C15487406 @default.
• W2225765013 hasConceptScore W2225765013C161790260 @default.
• W2225765013 hasConceptScore W2225765013C166940927 @default.
• W2225765013 hasConceptScore W2225765013C178790620 @default.

• next