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- W2225886558 abstract "In this chapter, we report on the shear rheology of suspensions and viscoelasticity of polymers filled with carbon nanosize particles (nanocomposites). The rheology of liquid suspension filled with well-dispersed and stabilized carbon nanotubes (CNTs) proves that the Brownian motion is the dominant mechanism of relaxation. Accordingly, dilute and semi-dilute suspensions of stabilized CNTs, cellulose whisker and polystyrene (PS) nanofibers respect a universal diffusion process according to the Doi–Edwards theory. Regarding fractal nanoparticles, two categories of nanoparticles can be considered: carbon black (CB) due to their native structure and exfoliated nanoparticles such as graphite oxide (GO) sheets and CNTs. The particular rheological behavior of these suspensions arises from the presence of the network structure (interparticle interaction), which leads to a drastic decrease in the percolation threshold and an increase in the conductive electrical properties. It was reported that the aggregation behavior is governed by the Brownian motion and local particle rearrangements under linear deformation. In the case of melt-filled polymers, the viscous forces are obviously the dominant forces and the nanoparticles, especially CNTs, are submitted to strong orientation under flow. Finally, we conclude with a qualitative discussion on the analogy between the variation of the shear modulus and the shear viscosity versus deformation and shear rate, respectively." @default.
- W2225886558 created "2016-06-24" @default.
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- W2225886558 date "2015-01-01" @default.
- W2225886558 modified "2023-10-06" @default.
- W2225886558 title "Rheology of Carbon Nanoparticle Suspensions and Nanocomposites" @default.
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- W2225886558 doi "https://doi.org/10.1016/b978-1-78548-036-2.50003-4" @default.
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