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- W2227111978 endingPage "3793" @default.
- W2227111978 startingPage "3785" @default.
- W2227111978 abstract "Abstract Easily accessible and tunable chiral triazoles have been introduced as a novel class of C−H bond‐based H‐donors for anion‐binding organocatalysis. They have proven to be effective catalysts for the dearomatization reaction of different N‐heteroarenes. Although this dearomatization approach represents a powerful strategy to build chiral heterocycles, to date only a few catalytic methods to this end exist. In this work, the organocatalyzed enantioselective Reissert‐type dearomatization of isoquinoline derivatives employing a number of structurally diverse chiral triazoles as anion‐binding catalysts was realized. The here presented method was employed to synthesize a number of chiral 1,2‐dihydroisoquinoline substrates with an enantioselectivity up to 86:14 e.r. Moreover, a thorough study of the determining parameters affecting the activity of this type of anion‐ binding catalysts was carried out." @default.
- W2227111978 created "2016-06-24" @default.
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- W2227111978 creator A5033028613 @default.
- W2227111978 date "2016-01-07" @default.
- W2227111978 modified "2023-10-03" @default.
- W2227111978 title "Chiral Triazoles in Anion-Binding Catalysis: New Entry to Enantioselective Reissert-Type Reactions" @default.
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- W2227111978 doi "https://doi.org/10.1002/chem.201504094" @default.
- W2227111978 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26743138" @default.
- W2227111978 hasPublicationYear "2016" @default.
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