FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2227991951> ?p ?o ?g. }

• W2227991951 endingPage "22403" @default.
• W2227991951 startingPage "22392" @default.
• W2227991951 abstract "The iodide/triiodide/iodine (I–/I3–/I2) redox system has been the subject of electrochemical investigations for well over half a century and remains a contemporary research interest due to the integral role of the I–/I3– couple in dye-sensitized solar cell (DSSC) technology. In this study, we have calculated the formal potential (E0′) of the I–/I2 process and the stability constant (Kstab) of I3– in two protic solvents (water and ethanol), two aprotic solvents (acetonitrile and propylene carbonate), eight aprotic ionic liquids (AILs), and one protic ionic liquid (PIL) using the voltammetric methodology developed herein. Furthermore, using 1-ethyl-3-methylimidazlium bis(trifluoromethanesulfonyl)imide (abbr. [C2mim][NTf2]) as a “model” ionic liquid-based DSSC electrolyte system, we have also investigated the influence of three common additives/impurities in DSSCs (i.e., tert-butylpyridine, Li+, and water) on the parameters E0′(I–/I2) and Kstab and characterized two analogous redox systems, Br–/Br3–/Br2 and SeCN–/(SeCN)3–/(SeCN)2. E0′(I–/I2) and Kstab(I3–) increase in the order ethanol ≈ acetonitrile < propylene carbonate < AILs < PIL < water; and water < ethanol ≈ PIL < acetonitrile ≈ AILs < propylene carbonate, respectively. In the presence of the additives/impurities (see above), E0′(I–/I2) and Kstab increase in the order 0.5 M tert-butylpyridine < neat [C2mim][NTf2] ≈ 0.3 M Li+ < 2 wt % water and 0.5 M tert-butylpyridine ≪ 2 wt % water < 0.3 M Li+ ≈ neat [C2mim][NTf2], respectively. Finally, E0′(X–/X2) and Kstab(X3–) increase in the order SeCN–/(SeCN)2 ≈ I–/I2 < Br–/Br2 and (SeCN)3– ≪ Br3– < I3–, respectively, in [C2mim][NTf2]. The trends in the (pseudo)halide/(pseudo)halogen formal potentials and tri(pseudo)halide stability constants have been rationalized in terms of the physicochemical parameters (i.e., polarity, Gutmann donor/acceptor numbers, ionic strength, etc.) of the respective solvent/ionic liquid media." @default.
• W2227991951 created "2016-06-24" @default.
• W2227991951 creator A5005521200 @default.
• W2227991951 creator A5015968146 @default.
• W2227991951 creator A5066751558 @default.
• W2227991951 creator A5067202566 @default.
• W2227991951 date "2015-09-16" @default.
• W2227991951 modified "2023-10-02" @default.
• W2227991951 title "Voltammetric Determination of the Iodide/Iodine Formal Potential and Triiodide Stability Constant in Conventional and Ionic Liquid Media" @default.
• W2227991951 cites W129762149 @default.
• W2227991951 cites W1861495197 @default.
• W2227991951 cites W1948217974 @default.
• W2227991951 cites W1965200916 @default.
• W2227991951 cites W1968553589 @default.
• W2227991951 cites W1973380066 @default.
• W2227991951 cites W1973724321 @default.
• W2227991951 cites W1977539440 @default.
• W2227991951 cites W1979600776 @default.
• W2227991951 cites W1980216394 @default.
• W2227991951 cites W1981582010 @default.
• W2227991951 cites W1982479518 @default.
• W2227991951 cites W1988566426 @default.
• W2227991951 cites W1989906055 @default.
• W2227991951 cites W1990411485 @default.
• W2227991951 cites W2004125971 @default.
• W2227991951 cites W2007449506 @default.
• W2227991951 cites W2011718083 @default.
• W2227991951 cites W2015649044 @default.
• W2227991951 cites W2019066434 @default.
• W2227991951 cites W2023828347 @default.
• W2227991951 cites W2028194922 @default.
• W2227991951 cites W2040465175 @default.
• W2227991951 cites W2041371644 @default.
• W2227991951 cites W2044376779 @default.
• W2227991951 cites W2049807213 @default.
• W2227991951 cites W2051665382 @default.
• W2227991951 cites W2052397896 @default.
• W2227991951 cites W2054450454 @default.
• W2227991951 cites W2057773621 @default.
• W2227991951 cites W2058908748 @default.
• W2227991951 cites W2060689376 @default.
• W2227991951 cites W2067410595 @default.
• W2227991951 cites W2070827317 @default.
• W2227991951 cites W2074701974 @default.
• W2227991951 cites W2076837591 @default.
• W2227991951 cites W2076901341 @default.
• W2227991951 cites W2089764168 @default.
• W2227991951 cites W2092129309 @default.
• W2227991951 cites W2093242360 @default.
• W2227991951 cites W2099113062 @default.
• W2227991951 cites W2116327492 @default.
• W2227991951 cites W2118514820 @default.
• W2227991951 cites W2166391935 @default.
• W2227991951 cites W2167356737 @default.
• W2227991951 cites W2280470130 @default.
• W2227991951 cites W2315819984 @default.
• W2227991951 cites W2322521838 @default.
• W2227991951 cites W2327633595 @default.
• W2227991951 cites W2328591207 @default.
• W2227991951 cites W4239450165 @default.
• W2227991951 cites W85495494 @default.
• W2227991951 doi "https://doi.org/10.1021/acs.jpcc.5b07484" @default.
• W2227991951 hasPublicationYear "2015" @default.
• W2227991951 type Work @default.
• W2227991951 sameAs 2227991951 @default.
• W2227991951 citedByCount "97" @default.
• W2227991951 countsByYear W22279919512016 @default.
• W2227991951 countsByYear W22279919512017 @default.
• W2227991951 countsByYear W22279919512018 @default.
• W2227991951 countsByYear W22279919512019 @default.
• W2227991951 countsByYear W22279919512020 @default.
• W2227991951 countsByYear W22279919512021 @default.
• W2227991951 countsByYear W22279919512022 @default.
• W2227991951 countsByYear W22279919512023 @default.
• W2227991951 crossrefType "journal-article" @default.
• W2227991951 hasAuthorship W2227991951A5005521200 @default.
• W2227991951 hasAuthorship W2227991951A5015968146 @default.
• W2227991951 hasAuthorship W2227991951A5066751558 @default.
• W2227991951 hasAuthorship W2227991951A5067202566 @default.
• W2227991951 hasConcept C147789679 @default.
• W2227991951 hasConcept C154881586 @default.
• W2227991951 hasConcept C161790260 @default.
• W2227991951 hasConcept C17525397 @default.
• W2227991951 hasConcept C178790620 @default.
• W2227991951 hasConcept C179104552 @default.
• W2227991951 hasConcept C185592680 @default.
• W2227991951 hasConcept C2777463227 @default.
• W2227991951 hasConcept C2777983707 @default.
• W2227991951 hasConcept C2778870691 @default.
• W2227991951 hasConcept C2779471803 @default.
• W2227991951 hasConcept C48421929 @default.
• W2227991951 hasConcept C52859227 @default.
• W2227991951 hasConcept C539932907 @default.
• W2227991951 hasConcept C68801617 @default.
• W2227991951 hasConceptScore W2227991951C147789679 @default.
• W2227991951 hasConceptScore W2227991951C154881586 @default.
• W2227991951 hasConceptScore W2227991951C161790260 @default.
• W2227991951 hasConceptScore W2227991951C17525397 @default.

• next