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- W2228242821 endingPage "2272" @default.
- W2228242821 startingPage "2267" @default.
- W2228242821 abstract "Several five-component nanorotors ROT-3 that rotate at different rates were prepared by adding phenanthrolines of distinct lateral size as brake blocks to the four-component nanorotor ROT-2. The brake blocks interfere with the 180° rotor causing the rotational frequency to drop from 97 kHz to 5 kHz. The effect of the rotating brake blocks on the rotational frequency in ROT-3 is accurately predicted by a nanomechanical model called “conformational slippage”. For quantification, the interaction of the brake blocks with the trajectory of the main rotator is gauged based on the number of interfering vs. non-interfering conformations as computed by PM6." @default.
- W2228242821 created "2016-06-24" @default.
- W2228242821 creator A5051082150 @default.
- W2228242821 creator A5063865324 @default.
- W2228242821 creator A5026089886 @default.
- W2228242821 date "2016-01-06" @default.
- W2228242821 modified "2023-10-03" @default.
- W2228242821 title "Conformational Slippage Determines Rotational Frequency in Five-Component Nanorotors" @default.
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- W2228242821 doi "https://doi.org/10.1002/anie.201509108" @default.
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