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• W2228577608 endingPage "412" @default.
• W2228577608 startingPage "403" @default.
• W2228577608 abstract "Abstract Seventeen compounds including the parent ortho ‐, meta ‐ and para ‐carboranes and derivatives of ortho ‐carborane were investigated for luminescence in cyclohexane and dichloromethane solutions. Fifteen of these carboranes revealed very weak emissions in the 285–493 nm range. These carboranes may arguably be viewed as non‐emissive in solutions at room temperatures. No emissions could be observed for 1,2‐dimethyl‐ ortho ‐carborane and 2‐methyl‐1‐phenyl‐ ortho ‐carborane. The carboranes with a 2′‐pyridyl substituent at the cluster carbon atom gave unusual local and charge‐transfer emissions indicating that different excited states are generated on photoexcitation. Of all the carboranes investigated, only 2‐(diphenylphosphino)‐1‐phenyl‐ ortho ‐carborane, 1,2‐diphenyl‐ ortho ‐carborane and 1‐phenyl‐2‐(2′‐pyridyl)‐ ortho ‐carborane are luminescent in the solid state with emissions at 476–612 nm and large Stokes shifts of 12000–13600 cm –1 . The solid‐state structures of 1,2‐bis(2′‐pyridyl)‐ and 1‐phenyl‐2‐(2′‐pyridyl)‐ ortho ‐carborane were determined by X‐ray crystallography." @default.
• W2228577608 created "2016-06-24" @default.
• W2228577608 creator A5018104738 @default.
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• W2228577608 creator A5082598321 @default.
• W2228577608 creator A5087624732 @default.
• W2228577608 date "2016-01-01" @default.
• W2228577608 modified "2023-10-10" @default.
• W2228577608 title "Substituent Effects on the Fluorescence Properties of <i>ortho</i> ‐Carbor­anes: Unusual Emission Behaviour in <i>C</i> ‐(2′‐Pyridyl)‐ <i>ortho</i> ‐carboranes" @default.
• W2228577608 cites W1512388082 @default.
• W2228577608 cites W1536143970 @default.
• W2228577608 cites W1573632704 @default.
• W2228577608 cites W1901669795 @default.
• W2228577608 cites W1966283008 @default.
• W2228577608 cites W1966414865 @default.
• W2228577608 cites W1967405310 @default.
• W2228577608 cites W1967775487 @default.
• W2228577608 cites W1967947382 @default.
• W2228577608 cites W1968469772 @default.
• W2228577608 cites W1968699656 @default.
• W2228577608 cites W1969405940 @default.
• W2228577608 cites W1969692210 @default.
• W2228577608 cites W1970153833 @default.
• W2228577608 cites W1972498086 @default.
• W2228577608 cites W1972928383 @default.
• W2228577608 cites W1973284434 @default.
• W2228577608 cites W1974730628 @default.
• W2228577608 cites W1975286659 @default.
• W2228577608 cites W1975433975 @default.
• W2228577608 cites W1975768604 @default.
• W2228577608 cites W1975842862 @default.
• W2228577608 cites W1976106306 @default.
• W2228577608 cites W1976325989 @default.
• W2228577608 cites W1977126599 @default.
• W2228577608 cites W1978996817 @default.
• W2228577608 cites W1982944045 @default.
• W2228577608 cites W1986913474 @default.
• W2228577608 cites W1989750308 @default.
• W2228577608 cites W1991140799 @default.
• W2228577608 cites W1991154902 @default.
• W2228577608 cites W1991306055 @default.
• W2228577608 cites W1992331113 @default.
• W2228577608 cites W1994496780 @default.
• W2228577608 cites W1994541961 @default.
• W2228577608 cites W1996788718 @default.
• W2228577608 cites W1996919150 @default.
• W2228577608 cites W1997266024 @default.
• W2228577608 cites W1999170908 @default.
• W2228577608 cites W2000296205 @default.
• W2228577608 cites W2001060666 @default.
• W2228577608 cites W2002724030 @default.
• W2228577608 cites W2003325773 @default.
• W2228577608 cites W2003353927 @default.
• W2228577608 cites W2004093781 @default.
• W2228577608 cites W2006976091 @default.
• W2228577608 cites W2010442741 @default.
• W2228577608 cites W2015165195 @default.
• W2228577608 cites W2017228753 @default.
• W2228577608 cites W2017278743 @default.
• W2228577608 cites W2018223635 @default.
• W2228577608 cites W2018328529 @default.
• W2228577608 cites W2020578264 @default.
• W2228577608 cites W2021134485 @default.
• W2228577608 cites W2023854383 @default.
• W2228577608 cites W2024034320 @default.
• W2228577608 cites W2025559763 @default.
• W2228577608 cites W2026398514 @default.
• W2228577608 cites W2027231500 @default.
• W2228577608 cites W2032308275 @default.
• W2228577608 cites W2032861082 @default.
• W2228577608 cites W2033668042 @default.
• W2228577608 cites W2034777072 @default.
• W2228577608 cites W2037170699 @default.
• W2228577608 cites W2039249400 @default.
• W2228577608 cites W2040402142 @default.
• W2228577608 cites W2041411743 @default.
• W2228577608 cites W2043662064 @default.
• W2228577608 cites W2044287989 @default.
• W2228577608 cites W2046234373 @default.
• W2228577608 cites W2048774271 @default.
• W2228577608 cites W2051262465 @default.
• W2228577608 cites W2053664614 @default.
• W2228577608 cites W2055917599 @default.
• W2228577608 cites W2056279372 @default.
• W2228577608 cites W2056965935 @default.
• W2228577608 cites W2059205366 @default.
• W2228577608 cites W2059376925 @default.
• W2228577608 cites W2060529015 @default.
• W2228577608 cites W2060702178 @default.
• W2228577608 cites W2064127006 @default.
• W2228577608 cites W2065430897 @default.
• W2228577608 cites W2072435511 @default.
• W2228577608 cites W2072639821 @default.

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