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• W2228926176 endingPage "1123" @default.
• W2228926176 startingPage "1108" @default.
• W2228926176 abstract "Palladium atoms generated by thermal evaporation and laser ablation were reacted with and trapped in F2/Ar, F2/Ne, and neat F2 matrices. The products were characterized by electronic absorption and infrared spectroscopy, together with relativistic density functional theory calculations as well as coupled cluster calculations. Vibrational modes at 540 and 617 cm–1 in argon matrices were assigned to molecular PdF and PdF2, and a band at 692 cm–1 was assigned to molecular PdF4. A band at 624 cm–1 can be assigned to either PdF3 or PdF6, with the former preferred from experimental considerations. Although calculations might support the latter assignment, our conclusion is that in these detailed experiments there is no convincing evidence for PdF6." @default.
• W2228926176 created "2016-06-24" @default.
• W2228926176 creator A5014730149 @default.
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• W2228926176 creator A5084138890 @default.
• W2228926176 date "2016-01-08" @default.
• W2228926176 modified "2023-09-27" @default.
• W2228926176 title "A Matrix Isolation and Computational Study of Molecular Palladium Fluorides: Does PdF₆ Exist?" @default.
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• W2228926176 doi "https://doi.org/10.1021/acs.inorgchem.5b02273" @default.
• W2228926176 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26745551" @default.
• W2228926176 hasPublicationYear "2016" @default.

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