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• W2229028538 endingPage "667" @default.
• W2229028538 startingPage "663" @default.
• W2229028538 abstract "Highly regioselective nucleopalladation for the oxidative coupling of internal alkynes with alkenyl alcohols by using green and low-costing oxygen as the sole oxidant was investigated. This one-pot cascade cyclization proceeds through Pd-catalyzed intramolecular C–O bond cyclization, insertion of nonbiased alkenyl alcohols, β-H elimination, and reinsertion of a HPdX species, which is finally transferred to the target ketones. This method has the advantages of mild conditions, good functional group tolerance, and can be performed with unactivated alkenes to afford isocoumarin derivatives." @default.
• W2229028538 created "2016-06-24" @default.
• W2229028538 creator A5006920141 @default.
• W2229028538 creator A5034933969 @default.
• W2229028538 creator A5045526093 @default.
• W2229028538 creator A5054489793 @default.
• W2229028538 creator A5088093835 @default.
• W2229028538 date "2016-01-05" @default.
• W2229028538 modified "2023-10-16" @default.
• W2229028538 title "Oxypalladation Initiating the Oxid­ative Heck Reaction with Alkenyl ­Alcohols: Synthesis of Isocoumarin-Alkanones" @default.
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