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- W2230279950 abstract "Cationic rhodium and iridium complexes incorporating mixed donor bidentate P,N ancillary ligands are effective in mediating certain homogeneous catalytic reactions. However, two disadvantages of cationic catalysts that potentially limit their synthetic utility include: (1) their poor solubility properties; and (2) the somewhat unpredictable nature of the outersphere counteranion on the catalytic performance of the complex. The development of alternative charge-neutral formally zwitterionic catalysts to overcome these challenges has received some attention, although the range of suitable anionic ligands to support Rh and Ir zwitterionic complexes remains limited. In the research presented in this thesis, a fundamentally new heterobidentate P,N ligand (1-P iPr2-2NMe2-indene, 2-2) has been prepared from readily available starting materials." @default.
- W2230279950 created "2016-06-24" @default.
- W2230279950 creator A5040410840 @default.
- W2230279950 date "2007-01-01" @default.
- W2230279950 modified "2023-09-23" @default.
- W2230279950 title "Synthetic, structural, and reactivity investigations of neutral, cationic, and zwitterionic rhodium(I), iridium(I), and manganese(I) derivatives of phosphorus,nitrogen-substituted indenes." @default.
- W2230279950 hasPublicationYear "2007" @default.
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