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- W2233133885 abstract "Abstract The green strengths of a gum SBR and two black-filled samples, at twenty-three volume percent filler, have been determined at various strain rates and temperatures. At higher temperatures, all samples exhibit yielding, followed by strain-softening. The gum exhibits this type of behavior down to −20°C, whereas, filled specimens undergo strain hardening at this temperature. Yield strength increases with decreasing temperature or increasing rate, indicating that it is largely controlled by chain mobility. Yield strengths at various temperatures may be shifted along the rate axis to form mastercurves. The dependence of yield stress on reduced rate is similar for the gum and the composition filled with the large-sized thermal black (N990). Stiffening is reasonably well accounted for by strain and strain-rate amplification, using the well-known Guth—Gold amplification factor. At low reduced rates, the extent of stiffening is substantially greater for samples filled with the much finer furnace black, N110. Unlike with the N990, SBR filled with N110 forms a coherent bound-rubber gel. This provides a strong resistance to deformation (beyond simple strain or strain-rate amplification) and results in high yield strength. At low temperatures, perhaps when the magnitude of chain—chain and chain—filler internal friction is comparable, the effect of filler size is greatly diminished." @default.
- W2233133885 created "2016-06-24" @default.
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- W2233133885 date "1992-05-01" @default.
- W2233133885 modified "2023-09-22" @default.
- W2233133885 title "Green Strength of Carbon-Black-Filled Styrene—Butadiene Rubber" @default.
- W2233133885 doi "https://doi.org/10.5254/1.3538625" @default.
- W2233133885 hasPublicationYear "1992" @default.
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