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• W2233329867 endingPage "83" @default.
• W2233329867 startingPage "73" @default.
• W2233329867 abstract "Over the years, gold catalysis has materialized as an incredible synthetic approach among the scientific community. Due to the trivial reaction conditions and great functional compatibility, these progressions are synthetically expedient, because practitioners can implement them to build intricate architectures from readily amassed building blocks with high bond forming indices. The incendiary growth of gold catalysts in organic synthesis has been demonstrated as one of the most prevailing soft Lewis acids for electrophilic activation of carbon-carbon multiple bonds towards a great assortment of nucleophiles. Nowadays, organic chemists consistently employ gold catalysts to carry out a diverse array of organic transformations to build unprecedented molecular architectures. Despite all these achievements and a plethora of reports, many vital challenges remain. In this account, we describe the reactivity of various gold catalysts towards cyclization processes developed over the years. These protocols give access to a wide scope of polyheterocyclic structures, containing different medium-sized ring skeletons. This is interesting, as the quest for highly selective reactions to assemble diversely functionalized products has attracted much attention. We envisage that these newly developed chemo-, regio-, and diastereoselective protocols could provide an expedient route to architecturally cumbersome heterocycles of importance for the pharmaceutical industry." @default.
• W2233329867 created "2016-06-24" @default.
• W2233329867 creator A5004992343 @default.
• W2233329867 creator A5033889570 @default.
• W2233329867 creator A5039474530 @default.
• W2233329867 creator A5052412003 @default.
• W2233329867 creator A5085401695 @default.
• W2233329867 date "2015-11-11" @default.
• W2233329867 modified "2023-10-18" @default.
• W2233329867 title "Gold-Catalyzed Cyclization Processes: Pivotal Avenues for Organic Synthesis" @default.
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