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- W2233834711 abstract "There are chemical compound classes, which are used as markers for different properties, reflecting the complexity of crude oil. Among these are the polycyclic aromatic sulfur heterocycles (PASHs), which play a major role among the constituents of petroleum and its refined products. This chapter provides recommendations that are directed particularly toward the characterization of PASHs for forensic purposes of any petroleum-derived pollutant that is likely to be encountered mainly in the marine environment and that arrived there through accident or oversight. Photo oxidation affects the aromatic compounds in crude oil and converts them to polar species of higher aqueous solubility. To identify the PASHs in environmental samples, the extract (or oil recovery) must not only be isolated from its particular matrix, but requires separation into specific fractions. Sulfur-selective detectors have not found much prominence in forensic studies where the mass selective detector is preferentially used, probably because the PASHs can be determined together with many other classes of compounds in one chromatographic run. Despite the fact that they are present in easily measured concentrations using routinely available techniques, some analytical quality considerations must not be overlooked." @default.
- W2233834711 created "2016-06-24" @default.
- W2233834711 creator A5010556311 @default.
- W2233834711 creator A5060666723 @default.
- W2233834711 date "2007-01-01" @default.
- W2233834711 modified "2023-09-27" @default.
- W2233834711 title "Characterization of polycyclic aromatic sulfur heterocycles for source identification" @default.
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- W2233834711 doi "https://doi.org/10.1016/b978-012369523-9.50008-2" @default.
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