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• W2234750672 abstract "To investigate the tendency of <TEX>$Li^+$</TEX> exchange from polar organic solvents, <TEX>$Li^+$</TEX>-ion exchange into zeolite Y (Si/Al = 1.56) was attempted by undried methanol (crystal 1) and formamide (crystal 2) solvent. Two single crystals of Na-Y were treated with 0.1 M LiNO3 in each of the two solvents at 323 K, followed by vacuum dehydration at 723 K. Their structures were determined by single-crystal synchrotron X-ray diffraction techniques in the cubic space group <TEX>$Fd{bar{3}}m$</TEX>, at 100(1) K. In both structures, <TEX>$Li^+$</TEX> for <TEX>$Na^+$</TEX> ions filled preferentially sites I' and II. The remaining <TEX>$Na^+$</TEX> ions occupied sites I', II, and III' in both structures, in additional to above sites, and <TEX>$Na^+$</TEX> ions occupied site I in crystal 2. While the 68 % exchange of <TEX>$Li^+$</TEX> for <TEX>$Na^+$</TEX> was achieved from undried methanol, only 40 % exchange was observed from undried formamide, indicating that the undried methanol was more effective than undried formamide as solvent for <TEX>$Li^+$</TEX> exchange under the conditions employed." @default.
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• W2234750672 date "2015-06-30" @default.
• W2234750672 modified "2023-10-03" @default.
• W2234750672 title "Characterization of Li+-ion Exchanged Zeolite Y using Organic Solvents" @default.
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• W2234750672 doi "https://doi.org/10.7745/kjssf.2015.48.3.180" @default.
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