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• W2234811979 endingPage "18723" @default.
• W2234811979 startingPage "18717" @default.
• W2234811979 abstract "Addition of organotrimethylsilane reagents to chiral N-tert-butanesulfinyl imines can be achieved in good yields and with excellent diastereoselectivities by employing TMSO(-)/Bu4N(+) as a Lewis base activator in THF. A variety of aliphatic, aromatic, heteroaromatic and organometallic chiral imines were utilised as electrophiles for the synthesis of enantioenriched N-tert-butanesulfinyl amides. Remarkably, the same sets of reaction conditions could be used with a highly diverse range of bench-stable organotrimethylsilane reagents, which highlights the generality and robustness of this methodology." @default.
• W2234811979 created "2016-06-24" @default.
• W2234811979 creator A5049288425 @default.
• W2234811979 creator A5074098727 @default.
• W2234811979 date "2015-11-12" @default.
• W2234811979 modified "2023-10-09" @default.
• W2234811979 title "Highly Selective Addition of a Broad Spectrum of Trimethylsilane Pro-nucleophiles to <i>N</i> -<i>tert</i> -Butanesulfinyl Imines" @default.
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• W2234811979 doi "https://doi.org/10.1002/chem.201503354" @default.
• W2234811979 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26558552" @default.
• W2234811979 hasPublicationYear "2015" @default.
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