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• W2234835862 abstract "Qualitative transformations of spectra of Electron Paramagnetic Resonance, EPR, were found in KH2PO4 crystals grown from liquor with 10−5–10−1 wt. % of anatase TiO2 nanoparticles in comparison with nominally pure KH2PO4. The nanoparticles have larger segregation coefficient for prismatic parts of the crystals than for pyramidal ones. Significant decrease in resonance absorption, complete disappearance of EPR lines of Fe3+ and Cr3+ centers, and appearance of four weak lines of equal intensities together with broad asymmetric lines with g-factors about 2.07–2.5 was observed in pyramidal parts grown with concentration of TiO2 nanoparticles larger than the threshold value 10−2 wt. %. The four lines were attributed to non-controlled impurity As substituted for P. In the presence of TiO2 nanoparticles, non-paramagnetic AsO43− clusters trap electrons becoming AsO44−. Disappearance of Fe3+ and Cr3+ centers was explained by their recharge to “EPR-silent” states and/or pairing at the surface of TiO2 nanoparticles." @default.
• W2234835862 created "2016-06-24" @default.
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• W2234835862 date "2016-01-15" @default.
• W2234835862 modified "2023-09-27" @default.
• W2234835862 title "Paramagnetic defects in KH2PO4 crystals with high concentration of embedded TiO2 nanoparticles" @default.
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• W2234835862 doi "https://doi.org/10.1063/1.4939731" @default.
• W2234835862 hasPublicationYear "2016" @default.
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