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• W2235956672 abstract "The advance in nanotechnology is mainly determined by the development of novel functionalized materials and the use of new principles of device functioning. The biomimetic approach may provide new insights in the design, development, assembly and functionalization of new intelligent materials and systems at the molecular level. The physical principles which drive the interactions leading to formation of self-assembled and self-organized molecular and nanoscopic systems have been widely investigated during the last years in order to establish a relation between chemical composition, structure and organization of these materials and systems with desired physical properties and functions. In this context, the Langmuir-Blodgett (LB) method is considered one of the most versatile techniques for fabricating organic thin films with well-controlled composition, structure and thickness. Due to these features, the LB technique has been widely used to handle and assemble different functional molecules in a predefined manner with the aim of, e.g., fabricating molecular devices, or investigating physicochemical processes occurring in the monolayer at the gas-substrate interface. The present chapter tries to describe the latest developments in the use of this technique to fabricate functional nanoassemblies. Typical Langmuir films consist of amphiphilic molecules with long alkyl chains that form organized assemblies at the air-water interface (or gas-liquid interface in general). When amphiphilic molecules are spread on a trough containing an aqueous subphase, they form a monolayer where the polar head group is immersed into the water and the hydrocarbon chain oriented toward the air, as depicted in Figure 1. The trough has a moving barrier controlled mechanically over the air-water interface that serves to reduce the surface area. As the monolayer is compressed, it will undergo several phase transitions that can be identified by monitoring the surface pressure as a function of the area occupied by the film (A). A typical isotherm can be observed in Figure 1." @default.
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• W2235956672 date "2006-01-09" @default.
• W2235956672 modified "2023-09-25" @default.
• W2235956672 title "New Applications and Properties of Langmuir-Blodgett Films" @default.
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• W2235956672 doi "https://doi.org/10.1007/0-306-48108-1_14" @default.
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