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- W2236703035 abstract "Cross sections for rotational transitions between various low-lying inversion doublets of NH/sub 3/ in collisions with CO/sub 2/, N/sub 2/, and H/sub 2/ are measured in a double-resonance beam maser setup. A modification of Anderson's theory (D. B. M. Klaassen, J. J. ter Meulen, and A. Dymanus, J. Chem. Phys. 77, 4972 (1982)) yields values for the cross sections that are in good agreement with the experimental results for CO/sub 2/ and N/sub 2/. For the system NH/sub 3/--H/sub 2/, transition probabilities are evaluated in Anderson's theory using ''bent'' trajectories. Induction and dispersion terms up to R/sup -7/ are considered in the long-range intermolecular potential. For the short-range repulsive part, two empirical potentials are proposed with parameters that are fitted to the experimental results. Integral cross sections for rotational transitions calculated with these potentials are also presented." @default.
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- W2236703035 date "1983-01-15" @default.
- W2236703035 modified "2023-09-23" @default.
- W2236703035 title "Beam maser investigation of inelastic scattering of NH/sub 3/. III. Cross sections for rotational transitions induced by CO/sub 2/, N/sub 2/, and H/sub 2/" @default.
- W2236703035 hasPublicationYear "1983" @default.
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