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• W2236772213 endingPage "1080" @default.
• W2236772213 startingPage "1077" @default.
• W2236772213 abstract "Non-natural, sequence-encoded polyphosphates were prepared using the phosphoramidite approach on a DNA synthesizer. Two phosphoramidite monomers, namely, 2-cyanoethyl (3-dimethoxytrityloxy-propyl) diisopropylphosphoramidite (0) and 2-cyanoethyl (3-dimethoxytrityloxy-2,2-dimethyl-propyl) diisopropylphosphoramidite (1), were used in this approach to form binary-coded sequences. Using 1000 Å controlled pore glass as a support and a large excess of monomers at each step, it was possible to synthesize homopolymers and sequence-coded copolymers of high chain-length. For instance, monodisperse polymers containing 16, 24, 56, and 104 coded monomer units were synthesized and characterized in this work. These results indicate that highly efficient phosphoramidite steps are suitable for the synthesis of long non-natural information-containing macromolecules." @default.
• W2236772213 created "2016-06-24" @default.
• W2236772213 creator A5006612391 @default.
• W2236772213 creator A5021687120 @default.
• W2236772213 creator A5047501404 @default.
• W2236772213 creator A5090844404 @default.
• W2236772213 date "2015-09-10" @default.
• W2236772213 modified "2023-10-18" @default.
• W2236772213 title "Synthesis of Monodisperse Sequence-Coded Polymers with Chain Lengths above DP100" @default.
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• W2236772213 doi "https://doi.org/10.1021/acsmacrolett.5b00606" @default.
• W2236772213 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35614807" @default.
• W2236772213 hasPublicationYear "2015" @default.
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