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- W2236836475 endingPage "435" @default.
- W2236836475 startingPage "432" @default.
- W2236836475 abstract "A ligand controlled selective hydroborylation of alkynes to α- or β-vinylboronates has been developed using a Pd catalyst. The high α-selectivity displayed by this reaction can be switched to furnish β-vinylboronates by altering the ligand from a trialkylphosphine to N-heterocyclic carbene. A variety of terminal alkynes are shown to furnish the corresponding α- or β-vinylboronates in good to excellent selectivity and yield. The mechanistic studies suggest that the solvent is the proton source and bromobenzene functions as an important additive in driving this reaction forward." @default.
- W2236836475 created "2016-06-24" @default.
- W2236836475 creator A5043633094 @default.
- W2236836475 creator A5044312898 @default.
- W2236836475 date "2016-01-13" @default.
- W2236836475 modified "2023-10-01" @default.
- W2236836475 title "Pd-Catalyzed Hydroborylation of Alkynes: A Ligand Controlled Regioselectivity Switch for the Synthesis of α- or β-Vinylboronates" @default.
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- W2236836475 doi "https://doi.org/10.1021/acs.orglett.5b03416" @default.
- W2236836475 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26760916" @default.
- W2236836475 hasPublicationYear "2016" @default.
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