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• W2236879797 abstract "A new 3D AgI-based coordination network, [Ag2(pz)(bdc)·H2O]n (1; pz = pyrazine and H2bdc = benzene-1,3-dicarboxylic acid), was constructed by one-pot assembly and structurally established by single-crystal X-ray diffraction at different temperatures. Upon cooling from 298 to 93 K, 1 undergo an interesting single-crystal to single-crystal phase transition from orthorhombic Ibca (Z = 16) to Pccn (Z = 32) at around 148 K. Both phases show a rare 2-fold-interpenetrated 4-connected lvt network but incorporate different [Ag2(COO)2] dimeric secondary building units. It is worth mentioning that complex 1 shows red- and blue-shifted luminescences in the 290–170 and 140–80 K temperature ranges, respectively. The variable-temperature single-crystal X-ray crystallographic studies suggest that the argentophilic interactions and rigidity of the structure dominated the luminescence chromism trends at the respective temperature ranges. Upon being mechanically ground, 1 exhibits a slight mechanoluminescence red shift from 589 to 604 nm at 298 K." @default.
• W2236879797 created "2016-06-24" @default.
• W2236879797 creator A5018121887 @default.
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• W2236879797 creator A5091645862 @default.
• W2236879797 date "2016-01-14" @default.
• W2236879797 modified "2023-10-17" @default.
• W2236879797 title "Single-Crystal to Single-Crystal Phase Transition and Segmented Thermochromic Luminescence in a Dynamic 3D Interpenetrated Ag^I Coordination Network" @default.
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• W2236879797 doi "https://doi.org/10.1021/acs.inorgchem.5b02200" @default.
• W2236879797 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26828950" @default.
• W2236879797 hasPublicationYear "2016" @default.
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