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- W223698714 abstract "Publisher Summary Pulse radiolysis methodology is based on the fact that water molecules are split by ionizing irradiation into a variety of reactive radicals. If irradiation is applied as a pulse, whose duration is short relative to the lifetime of the produced radicals, the reactions can be followed by proper registration techniques on a real-time basis. Limitations to the pulse radiolysis technique only exist if the intermediates in a reaction chain absorb very poorly or when the absorptions caused by several species, which are present at the same time, spectrally overlap. In these cases, the method of competition analysis may be used. The most powerful advantages of the pulse radiolysis technique become evident if specific radicals have to be generated in reproducible quantities under standardized conditions. This may be achieved either by reduction, which is easily performed by the smallest reducing entity that exists, the hydrated or solvated electron, or by oxidation, which is efficiently effected by one of the most powerful oxidants known in chemistry, “the hydroxyl radical” (•OH )." @default.
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- W223698714 date "1994-01-01" @default.
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- W223698714 title "[2] Pulse radiolysis for investigation of nitric oxide-related reactions" @default.
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- W223698714 doi "https://doi.org/10.1016/s0076-6879(94)33005-0" @default.
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