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• W2237177730 abstract "A highly efficient and stable Rh–P catalytic system in the RTIL of [PEmim]BF₄ was developed for the biphasic hydroformylation of 1-octene by using the diphosphine-functionalized ionic liquid (FIL) of <bold>2</bold>. While <bold>2</bold>-Rh(acac)(CO)₂ was immobilized in [PEmim]BF₄ (solvent), a typical biphasic catalysis was fulfilled with advantages of facile separation and recycling ability – 9 runs without any loss of activity. It was found that not only the acquired π-acceptor character of <bold>2</bold>, but also the synergetic role of the piperidyl group in [PEmim]BF₄ as an N-containing donor, cooperatively contributed to the efficient hydroformylation due to the facilitated formation and stability of the Rh-H active species (<italic>ν</italic> 2045 cm⁻¹). This was supported by the <italic>in situ</italic> high-pressure FT-IR spectral analysis." @default.
• W2237177730 created "2016-06-24" @default.
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• W2237177730 date "2016-01-01" @default.
• W2237177730 modified "2023-10-16" @default.
• W2237177730 title "Immobilization of a rhodium catalyst using a diphosphine-functionalized ionic liquid in RTIL for the efficient and recyclable biphasic hydroformylation of 1-octene" @default.
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• W2237177730 doi "https://doi.org/10.1039/c5fd00195a" @default.
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